Removal of Chromium (VI) from Water Using Orange peel as the Biosorbent: Experimental, Modeling, and Kinetic Studies on Adsorption Isotherms and Chemical Structure

Abstract

The present work aims to assess the effectiveness and efficiency of orange peels as a low-cost biosorbent for removing Cr(VI) from an aqueous solution by the biosorbent process. The orange peels as adsorbent was characterized using different methods, such as FTIR, pHpzc, equilibrium pH, TGA, XRD, SEM, and (BET). The tests were conducted in the batch mode, and the effects of different parameters, such as the pH, dosage of the bioadsorbent, influent Cr(VI), and time, on the biosorption of Cr(VI) were investigated. The adsorption kinetics proved that a contact time of 90 min resulted in the highest (approximately 97.8%) Cr(VI) removal, with an adsorption capacity of 4.96 mg/g. Moreover, the increase in the biosorbent dosage (from 1 to 10 g/L) resulted in the enhancement in the Cr(VI) removal effectiveness. Moreover, the pH of the solution also affected significantly the effectiveness of the removal. The tests were conducted under acidic pH solution conditions, and the prediction of the pH value at a zero charge (pH pzc) was confirmed experimentally. Furthermore, the results from the batch-mode assays were successfully tested by an experimental design (full factorial design). The biosorption of Cr(VI) on orange peels occurred mostly according to the pseudo-second-order kinetic model and the uptake of Cr(VI) was satisfactorily described by the Langmuir model.