Waste plastic differs in its speed of combustion owing to its variety in composition as well as kinds of plastic. This study is aimed at examining the thermal weight analysis and determination of its kinetics in order to derive the design element in pyrolysis of RPF (Refused Plastic Fuel) as the plastic solid fuel. Based on the result of TGA (Thermogravimetric analysis), kinetic characteristics were analyzed by using Kissinger method which are the most common method for obtaining activation energy, and experimental conditions of TGA were set as follows: in a nitrogen atmosphere, gas flow rate of 20 ml/min, heating rate of 5~50 o C/min, and maximum hottest temperature of 800 o C. The method used for determining the property of waste plastic when thermally decomposed was thought feasible as the basic data in deciding the performance, design, and optimal operating condition of the reactor in the actual reactor.