The combustion stoichiometry or air to fuel ratio is a critical operating parameter inn many processes. The stoichiometry and thus the combustion efficiency dictates the plant economics as well as the environmental impact. In this work the technique of Fourier transform infrared spectroscopy has been evaluated as a non-intrusive probe of CO and CO2 concentrations, average line of sight temperatures and temperature profiles on a 500 Kw oilfired combustion test facility. Results have been compared with facility temperatures and concentrations calculated from an equilibrium chemistry model. Both FTIR emission and absorption configurations were evaluated thereby allowing conclusions as to the potential of these techniques for large scale facility diagnostics. CO2 concentrations and profile temperatures were observed to agree well with the facility measurements and chemistry calculations. CO concentrations were observed to be in poor agreement with the calculations. This result is believed to arise form incomplete mixing in the test facility burner although other facility effects cannot be ruled out. The presence of CO in the spectra at an air to fuel ratio of 1.05 indicates that the FTIR methods can be used to diagnose burner operation.
INTRODUCTIONA critical operating parameter for combustion-drive facilities such as advanced coal-fired power plants, incinerators, and rotary kilns is the burner air to fuel ratio or stoichiometry, q. At a stoichiometry of 1, for a simple hydrocarbon fuel, the principle combustion products will be CO2 and H2O. Combustion temperatures will be maximized. Decreasing p below 1 results in lower temperatures through the inefficient use of the fuel and thus the formation of products of incomplete combustion (PICs) such as CO and methane. At stoichiometries greater than 1, the excess air will result in cooler combustion temperatures although the reactions will proceed to completion. Burner stoichiometry therefore controls the environmental impact of the facility as well as the process economics. Higher combustion temperatures lead to increased heat transfer in downstream facility sections.The air to fuel ratio can be calculated from knowledge of the fuel composition and input feed rates. Following combustion an efficiency can he defined as