Remarkable tailoring of thermal and dielectric properties of poly(vinyl alcohol) nanocomposite via hydrothermal grown ZnAl layer di hydroxide nanostructures and graphene fillers

Abstract

In this work, we have synthesized the zinc‐aluminum layered double hydroxide (ZnAl LDH) nanostructures using cost‐effective hydrothermal technique. The ZnAl LDH and graphene‐based poly(vinyl alcohol) (PVA) nanocomposites are fabricated. The crystal structure, morphology, thermal, and dielectric properties of pristine PVA and ZnAl LDH and graphene‐based PVA nanocomposites films were investigated using X‐ray diffraction, HR‐transmission electron microscopy, thermo gravimetric analysis, and impedance analyzer. HRTEM analysis reveals the hexagonal nanoplates shape‐like morphology of Zn‐Al layered double hydroxides with an average thickness of 40–50 nm and size of 400–600 nm. High thermal stability was observed from ZnAl LDH and graphene‐reinforced nanocomposite. Enhanced thermal stability of 250°C and low weight loss was observed from ZnAl LDH reinforced PVA‐based nanocomposites compared to pristine PVA. Zn‐Al LDH nanoplates‐graphene‐PVA based nanocomposites showed ultra‐high dielectric constant (ɛ′) of 794 as compared to the ZnAl LDH‐PVA nanocomposites (ɛ′ ~ 334) and pristine PVA sample (ɛ′ ~ 35). Low dielectric loss of 0.27, 0.18, 0.38 was observed for pristine PVA, ZnAl‐LDH‐PVA and ZnAl‐LDH‐graphene‐PVA nanocomposites. The large enhancement of the dielectric constant and thermal stability were discussed in terms of improved crystallinity, interfacial polarization and formation of nanodipoles in the matrix. This study reveals a significant role of LDH‐graphene‐based hybrid nanocomposites in optoelectronics, energy storage, sensors, energy conversion and thermally stable devices.Highlights Growth of highly crystalline zinc‐aluminum layered double hydroxide nanostructures. Improved thermal stability for Zn‐Al LDH‐graphene‐PVA nanocomposites. High thermal stability from ZnAl LDH‐based PVA nanocomposites. Ultra‐high dielectric constant of 794 is observed from Zn‐Al LDH nanoplates‐graphene‐nanocomposites.

The theoretical and experimental buckling analysis of a nanocomposite beams reinforced by nanorods made of recycled materials

“…[9][10][11][12] After the discovery of carbon nanotubes (CNTs) by Ijima, 13 carbon nanostructures are attracted the attention of researchers due to their large Young's modulus, yield strength, flexibility, and conductive properties. [14][15][16] Also, adding various types of carbon nanostructures to the matrix of the composite structures, compensates and improves the structural inherent defects, and improves the properties of the composite structure. [17][18][19][20] Due to the widespread use of reinforced composites under different loading conditions, the compressive behavior of these composites is one of the main concerns for design in engineering applications.…”