2021
DOI: 10.1039/d1re00277e
|View full text |Cite
|
Sign up to set email alerts
|

Remarkable improvement of epoxide ring-opening reaction efficiency and selectivity with water as a green regulator

Abstract: Glycidyl esters are synthesized through the epoxide ring-opening reactions, and the reaction efficiency must be greatly improved for green and efficient production. In this work, the structure of the side...

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
2
2
1

Citation Types

0
15
0

Year Published

2022
2022
2024
2024

Publication Types

Select...
5

Relationship

1
4

Authors

Journals

citations
Cited by 10 publications
(16 citation statements)
references
References 23 publications
0
15
0
Order By: Relevance
“…Deionized water as another stream, it plays an important role to improve the selectivity, the mechanism and experimental evidence have been presented in detail in our previous research. 10 In Section 3.3 of this work, the effect of water on selectivity was also briefly discussed. The three streams, NDA (with TMAN dissolved), ECH, and water, were delivered by three syringe pumps (Chemyx Fusion 6000).…”
Section: Experimental Procedures and Set-upsmentioning
confidence: 99%
See 4 more Smart Citations
“…Deionized water as another stream, it plays an important role to improve the selectivity, the mechanism and experimental evidence have been presented in detail in our previous research. 10 In Section 3.3 of this work, the effect of water on selectivity was also briefly discussed. The three streams, NDA (with TMAN dissolved), ECH, and water, were delivered by three syringe pumps (Chemyx Fusion 6000).…”
Section: Experimental Procedures and Set-upsmentioning
confidence: 99%
“…This side reaction pathway is more sensitive to temperature than the acid-base reaction, so the formation of EPDA is more obvious at higher temperature. 10 As the downstream targeted product, the formation of EPDA does not affect the selectivity. However, as shown Figure 2C, EPDA can further react with NDA via the same catalytic route as the main reaction of ECH with NDA, leading to the formation of diester.…”
Section: Side Reactionsmentioning
confidence: 99%
See 3 more Smart Citations