Remarkable effects of silicone rubber on flame retardant property and mechanical properties of crosslinked high‐density polyethylene/bio‐based magnesium phosphate flame retardant (MHPA) composite

Abstract

In this paper, a new bio‐based flame retardant MHPA was prepared by the reaction of magnesium hydroxide (MH) and phytic acid (PA). Then the crosslinked high‐density polyethylene (HDPE) flame‐retardant composite was prepared by adding it and silicone rubber (SR) into HDPE and using electron beam irradiation. The test results of limiting oxygen index (LOI) and cone calorimeter test (CCT) show that the combination of MHPA and SR can increase the flame retardancy and smoke suppression performance of HDPE. The LOI of HDPE composite with 10 parts of SR is 28.3%, and its pHRR, THR and TSP values are reduced to 454.1 kW/m2, 99.7 MJ/m2 and 8.3 m2, respectively, which is because MHPA and SR jointly promote the formation of continuous and high‐density carbon slag in the combustion process of HDPE and inhibit the penetration of flame. In addition, the HDPE composite with 10 parts of SR has significant tensile strength, elongation breaking strength and tear strength, because SR can produce continuous stable structure with HDPE after irradiation and crosslinking. Therefore, this study verified that MHPA and SR together can effectively improve the flame retardancy, smoke suppression and mechanical properties of HDPE composite.

Intercalation of silsesquioxane surfactant in layered double hydroxide for silicone rubber composites: Enhancing interfacial interactions toward improvement of mechanical, thermal, and gas barrier properties

“…Moreover, the superhydrophilicity of LDHs results in agglomeration and poor distribution in polymer matrices, reducing the mechanical properties of the materials. [14][15][16] In the past decade, various approaches have been implemented to improve the dispersion of LDHs, including surface chemical modification, interlayer intercalation, and exfoliation of LDHs. Among these methods, surface decoration or modification with organic anions can significantly improve the dispersion of LDH nanoparticles within polymer matrices.…”

“…However, LDHs are difficult to delaminate because of the high charge density of the layers and anion content. Moreover, the superhydrophilicity of LDHs results in agglomeration and poor distribution in polymer matrices, reducing the mechanical properties of the materials 14–16 …”