The detection of the free precession of co-located 3 He/ 129 Xe nuclear spins (clock comparison) is used as ultra-sensitive probe for non-magnetic spin interactions, since the magnetic dipole interaction (Zeeman-term) drops out in the weighted frequency difference, i.e., ω = ω He -
Features of frequency standards and clocksSince Galileo Galilei and Christiaan Huygens invented the pendulum clock, time and frequency have been the quantities that we can measure with the highest precision. Since 1967 the Cs atomic clock defines our unit of time, the second, as the period during which a cesium-133 atom oscillates 9,192,631,770 number of cycles on the hyperfine clock transition |F = 4, m F = 0 → |F = 3, m F = 0 in the 6 2 S 1/2 atomic ground state. Cesium atomic clocks have been gradually improved to the point where modern cesium-fountain clocks realize the definition of the second with a relative uncertainty of about 4 × 10 −16 [1]. In the near future, the cesium clock defining the fundamental timing reference will be replaced with an optical clock, since suppression of systematic effects shifting the frequency of a standard is greatly facilitated by the use of higher frequencies.Thanks to the incredible high relative accuracy of frequency determination, atomic clocks may touch the μHz range on an absolute scale, but will essentially not go far below.To address fundamental questions in physics often associated with the experimental search for violation of fundamental symmetries in nature, much smaller frequencies or frequency shifts as a result of tiny changes in the clock transition must be tracked. From that point of view it is more appropriate to develop a "clock" that oscillates at low frequencies (∼10 Hz), but shows the same relative accuracy as a Cs atomic clock. Thus, frequency shifts in the pHz range caused by hypothetical interaction potentials might be accessible."Spin clocks" which are based on nuclear spin precession are the most promising approach to reach such sensitivity limits. The ,,spin clock" described here is based on the detection of free spin-precession of gaseous, nuclear spin-polarized 3 He or 129 Xe samples [2]. Like in a free induction decay (FID) measurement, the decay of the transverse magnetization is monitored and the Larmor frequency ω of the precessing sample magnetization is related to the magnetic field B 0 through ω = γ · B 0 , where γ is the gyromagnetic ratio of the corresponding nucleus. Since this type of clock will preferably operate at low magnetic fields and thus at low frequencies, using a SQUID as magnetic field detector is appropriate due to its high sensitivity in that spectral range. The 3 He/ 129 Xe nuclear spins are polarized by means of optical pumping. Thus, the nuclear polarization obtained exceeds the Boltzmann polarization as used in typical NMR experiments by four to five orders of magnitude.