Relative thermal stability of metal soaps of Ximenia americana and Balanites aegyptiaca seed oils

Abstract

Metal soaps of Ximenia americana seed oil (XSO) and Balanites aegyptiaca seed oil (BSO) were prepared by metathesis in aqueous alcohol solution. The thermal stability of the metal carboxylates (soaps) was studied thermogravimetrically in the temperature range 50 -500°C under nitrogen. The thermal stability of the carboxylates was assessed in terms of temperatures at which various extents of decomposition were attained and weight loss at the initial stage of decomposition. The weight loss for all the metal soaps was less than 10% at temperature up to 250°C. The activation energies at the initial stage of decomposition of the metal carboxylates modelled using Broido's equation are in the range 6.93 -14.14 kJmol -1 for XSO while those of BSO ranged between 15.52 -28.41 kJmol -1. Based on these results, metal soaps of BSO are thermally stable than those of the corresponding XSO soaps. The results suggest potential application of carboxylates of X. americana and B. aegyptiaca seed oils in some industrial applications.

Synthesis and characterization of copper metal soaps from Thevetia peruviana and Hura crepitans seed oils

“…CH 2 antisymmetric and symmetric stretching vibrations occur with varying intensities in the region 2926 to 2927 cm -1 for T. peruviana and H. crepitans oils, respectively and between 2857 and 2922, 2857 and 2925 cm -1 for the metal soaps, respectively. Typical antisymmetric stretching vibration for carboxylate occurs between 1589 and 1611 cm -1 (Olujinmi et al, 2011). The difference in absorption frequencies of carbonyl group of fatty acid and its corresponding metal soap also confirms the formation of soaps.…”