Relative reactivity of N,N-donor ligands in substitution reactions of cis-diaqua(2-aminomethylpiperidine)platinum(II): a detailed kinetic and mechanistic study
Abstract:The reactivity of cis-[Pt(pipen)(H 2 O) 2 ] 2+ (pipen = 2-aminomethylpiperidine) was investigated by studying the interaction with some didentate N,N-donor ligands, namely, dimethylglyoxime (L 1 H), 1,2cyclohexanedionedioxime (L 2 H) and α-furildioxime (L 3 H) in an aqueous medium. All the above substitution reactions have been monitored spectrophotometrically at 320, 308 and 290 nm, respectively, where the spectral difference between the reactants and the products are appreciable. The kinetic study has been s… Show more
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