Relationship between Structure and Zero-Field Splitting of Octahedral Nickel(II) Complexes with a Low-Symmetric Tetradentate Ligand
Hiroshi Sakiyama,
Rin Kimura,
Haruto Oomiya
et al.
Abstract:Octahedral nickel(II) complexes are among the simplest systems that exhibit zero-field splitting by having two unpaired electrons. For the purpose of clarifying the relationship between structure and zero-field splitting in a low-symmetric system, distorted octahedral nickel(II) complexes were prepared with a tetradentate ligand, 2-[bis(2-methoxyethyl)aminomethyl]-4-nitrophenolate(1−) [(onp)−]. The complex [Ni(onp)(dmso)(H2O)][BPh4]·2dmso (1) (dmso = dimethyl sulfoxide) was characterized as a bulk sample by IR… Show more
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