The effects of MOx (M=Al, Ti, Zr) addition on the microstructure, crystallization behavior and optical properties of ZnO-MOx films deposited by sol-gel method were investigated. Zinc acetate dihydrate (Zn(OCOCH 3 h · 2H 2 0), ethanolamine and 1-propanol were used as a starting material, stabilizer and solvent, respectively. Aluminum sec-butoxide, titanium i-propoxide and zirconium n-propoxide were used as MOx sources. The surface morphology of ZnO-MOx films fired at 500oC depended on the kind of MOx. In ZnO-Al01.5 film, the corrugated structure and cracks were observed. In contrast, the surface of Zn0-Zr0 2 film was flat with no crack. The grain size of the Zn0-Zr0 2 film was large (approximately 80 nm) compared with ZnO-Al01.5 and ZnO-Ti0 2 films. The higher crystallinity was obtained in Zn0-Zr0 2 ([Zn]/[Zr]=80/20) film compared with other ZnO-MOx films. The addition of Al01.5 or Ti0 2 resulted in the suppression of grain growth and crystallization in the films. As a result, only Zn0-Zr0 2 ([Zn]/[Zr]=80/20) film exhibited higher transmittance ("--'90%) in the visible region and higher shielding property (>90%) in the ultraviolet ray regwn.