2011
DOI: 10.1016/j.jms.2011.02.014
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Reinvestigation of the microwave and new high resolution far-infrared spectra of cis-methyl nitrite, CH3ONO: Rotational study of the two first torsional states

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Cited by 4 publications
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“…The unusual iso-coordinated long bonding, similar to HOON, was computationally predicted to exist in its methyl-containing analogue, CH 3 OON . Its isomers, methyl nitrite and nitromethane, are important model energetic materials that could be used as explosives and propellants, , and many studies focused on understanding the reaction mechanisms and kinetics of processes involving these compounds. , For example, the infrared multiphoton decomposition study by Wodtke, Hintsa, and Lee in 1986 reported that bond dissociation and isomerization of CH 3 NO 2 could produce CH 3 • + NO 2 • and CH 3 O • + NO • (through CH 3 ONO), respectively. The CH 3 NO 2 isomerization energy is 1.5 kcal/mol lower than the C–N bond dissociation energy, suggesting that CH 3 O • + NO • should be a kinetically more favorable product.…”
Section: Introductionmentioning
confidence: 99%
“…The unusual iso-coordinated long bonding, similar to HOON, was computationally predicted to exist in its methyl-containing analogue, CH 3 OON . Its isomers, methyl nitrite and nitromethane, are important model energetic materials that could be used as explosives and propellants, , and many studies focused on understanding the reaction mechanisms and kinetics of processes involving these compounds. , For example, the infrared multiphoton decomposition study by Wodtke, Hintsa, and Lee in 1986 reported that bond dissociation and isomerization of CH 3 NO 2 could produce CH 3 • + NO 2 • and CH 3 O • + NO • (through CH 3 ONO), respectively. The CH 3 NO 2 isomerization energy is 1.5 kcal/mol lower than the C–N bond dissociation energy, suggesting that CH 3 O • + NO • should be a kinetically more favorable product.…”
Section: Introductionmentioning
confidence: 99%