Regulations of the Influence of External Thermal Influences on Speed and Explosive Safe Combustion Modes of Pyrotechnic Nitrate-Metallized Mixtures with Metal Fluoride

Abstract

A study was made of the regularities of the influence of the main parameters of external thermal effects (elevated heating temperatures and external pressures) on the rate and explosive modes of combustion development of compacted mixtures of magnesium, aluminum and sodium nitrate with fluoride additives metals for different values of technological parameters (excess ratio of the oxidizing agent, nature and content of the additive, dispersion of the components). The effect of technological parameters (ratio and dispersion of components, compaction coefficient, charge diameter, shell material, etc.) on the dependence of the burning rate of mixtures on elevated heating temperatures and external pressures was established; critical ranges of changes in these parameters are determined, the excess of which leads to premature explosive development of combustion of mixtures and fire hazardous destruction of products. On the basis of the research, methods were developed to prevent these destructions of products by regulating technological parameters at the stage of preparation of charge mixtures, which increases the stability of the combustion process of mixtures to external thermal influences. A database has been obtained on the burning rates of compacted mixtures of metal powders (Mg, Al), nitrate-containing oxidizer (NaNO3 ) and additives of inorganic substances (metal fluorides (LiF, NaF, BaF2 , SiF2 , SrF2 , AlF3 )) under conditions elevated heating temperatures and external pressures for various values of technological parameters, which makes it possible to determine the explosive modes of their combustion.