Abstract:1,2-Bifunctional ligands are rare, in general, which holds especially for those with a P-N linkage. Herein, we report on the synthesis of P-tert-butyl substituted aminophosphane W(CO)5 complexes 3a-f (a: R = R’ = H; b: R = H, R = Me; c: R = H, R’ = ally; d: R = H, R’ = i-Pr; e: R = H, R’ = t-Bu; f: R = R’ = Me) obtained via formal N-H insertion reactions of Li/Cl phosphinidenoid complex 2 into NH bonds of ammonia and different amines. The 1,2-bifunctionality of 3b was addressed in targeted regioselective depro… Show more
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