Regio- and stereocontrolled synthesis and Diels-Alder reactions of (Z)-2-(phenylthio)-1-(trimethylsilyl)-1,3-butadiene

Chou, Shang‐Shing P.; Chao, Mao‐Hsun

doi:10.1016/0040-4039(95)01884-k

Cited by 12 publications

References 25 publications

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Formation of Alkenes by Diels–Alder Reactions

Larock

2018

Comprehensive Organic Transformations

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General Reviews Regioselectivity Exo / Endo Selectivity Asymmetric Diels–Alder Reaction Mechanism Use of High Pressure Microwave Irradiation Infrared Irradiation Mechanical Ball Milling Ultracentrifugation Use of Ultrasound Catalysis Solvent Effects Cavity Effects Retro‐Diels–Alder Reaction Intramolecular Diels–Alder Reaction Inverse Electron‐Demand Diels–Alder Reaction Radical Cation Diels–Alder Reaction Ionic Diels–Alder Reaction Use of Heterodienophiles Use of Heteroatom‐Containing “Dienes” Use of Substituted 1,3‐Dienes o ‐Quinodimethanes and Heterocyclic Analogues Arynes and Hetarynes Some Other Dienophiles Dienophile Equivalents Transition Metal Carbenes as Dienophiles

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Formation of Alkenes by Diels–Alder Reactions

Larock

2018

Comprehensive Organic Transformations

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ChemInform Abstract: Regio‐ and Stereocontrolled Synthesis and Diels‐Alder Reactions of (Z)‐ 2‐(Phenylthio)‐1‐(trimethylsilyl)‐1,3‐butadiene.

Chou

Chao

1996

ChemInform

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Regioselective Synthesis of 5‐(Arylsulfanyl)‐ and 5‐(Benzylsulfanyl)‐6‐phenylsalicylates by One‐Pot Cyclizations of 1,3‐Bis(silyloxy)buta‐1,3‐dienes with 2‐(Arylsulfanyl)‐ and 5‐(Benzylsulfanyl)‐3‐ethoxy‐1‐phenylprop‐2‐en‐1‐ones

Fatunsin¹,

Shkoor²,

Riahi³

et al. 2010

Helvetica Chimica Acta

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5-(Arylsulfanyl)-6-phenylsalicylates were prepared by one-pot cyclizations of 1,3-bis(trimethylsilyloxy)buta-1,3-dienes with 2-(arylsulfanyl)-3-ethoxy-1-phenylprop-2-en-1-ones.1. Introduction. -Natural and non-natural diaryl sulfides (diaryl thioethers) are of pharmacological relevance and have been isolated as natural products (for dibenzothiophenes, see . Mild metal-catalyzed and metal-free reactions for the synthesis of diaryl sulfides have also been reported [4 -6]. These methods are often limited by the fact that highly substituted and sterically encumbered products are not readily available. In addition, the synthesis of the starting materials, substituted arenes and thiophenols, can be difficult.The use of S-containing building blocks in cyclization reactions (building-block approach) provides an alternative procedure to diaryl sulfides. This approach involves the assembly of the arene moiety by formation of two CÀC bonds. Hilt and co-workers reported an efficient synthesis of diaryl sulfides by Co

show abstract

Regio- and stereocontrolled synthesis and Diels-Alder reactions of (Z)-2-(phenylthio)-1-(trimethylsilyl)-1,3-butadiene

Cited by 12 publications

References 25 publications

Formation of Alkenes by Diels–Alder Reactions

Formation of Alkenes by Diels–Alder Reactions

ChemInform Abstract: Regio‐ and Stereocontrolled Synthesis and Diels‐Alder Reactions of (Z)‐ 2‐(Phenylthio)‐1‐(trimethylsilyl)‐1,3‐butadiene.

Regioselective Synthesis of 5‐(Arylsulfanyl)‐ and 5‐(Benzylsulfanyl)‐6‐phenylsalicylates by One‐Pot Cyclizations of 1,3‐Bis(silyloxy)buta‐1,3‐dienes with 2‐(Arylsulfanyl)‐ and 5‐(Benzylsulfanyl)‐3‐ethoxy‐1‐phenylprop‐2‐en‐1‐ones

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