Poly (Vinyl Alcohol)/Copper Chloride (PVA/CuCl and 20 wt% of CuCl 2 . UV-Vis spectrum of these composites is investigated in the range of 200 spectrum of PVA showed an absorption band at 278.18 nm and a small shoulder at 313.09 nm and are assigned to * transition, respectively. On the other hand, the spectra of the PVA/CuCl resonance (SPR) band in the visible band at 778.07 nm. Moreover, it is observed that, the absorption edge of composite samples is red shifted. Also, pure PVA showed an which decreased to 3.48 and 3.92 eV after CuCl also observed that nonlinear optical parameters such as thi refractive index (n 2 ) are influenced by CuCl These results are very encouraging for possible applications constant ( ' ), dielectric loss ( '' ) and photoconductivity have been investigated