Reduction of CO Content in Hydrogen Rich Fuel by CO Electrolytic Oxidation for Reformed Gas Fueled PEFCs

Maeda, Hideo; Fukumoto, Hisatoshi; Mitsuda, Kenro

doi:10.5796/electrochemistry.70.615

Cited by 10 publications

(1 citation statement)

References 6 publications

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“…At this stage, researchers have further explored the multiple applications of pulse electrolysis based on its first periods, such as pulse electrolysis of water, CO 2 , pulse-radiolysis, electrodeposition, and oxidation. Moreover, the appropriate pulse parameters in different applications have been investigated and confirmed the advantages of pulse over constant potential electrolysis [60][61][62]. A representative work in this stage was pulsed electrodeposition for the preparation of metallic materials [46], where the merits of accelerating the deposition of metals, improving current efficiency, and producing metallic materials with a dense structure and a smooth and bright finish have been found.…”

Section: Historical Analysis Of Pulsed Electrolysis Via a Bibliometri...mentioning

confidence: 84%

A Bibliometric Analysis on Pulsed Electrolysis: Electronic Effect, Double Layer Effect, and Mass Transport

Wang,

Liu,

Liu

et al. 2023

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Pulsed electrolysis endowed merits of high current density, low energy consumption, and simple operation; thus, a booming in their publication numbers has been witnessed in recent years. In this review, we aim to summarize the state-of-the-art pulsed current/potential strategy to enhance electrochemical reactions, such as oxygen reduction reactions (ORR), CO2 reduction (CO2RR), CO reduction (COR), etc. It begins with historic analysis of pulsed electrolysis via a bibliometric method, aiming at providing a progress over the course of around 40 years in a quantitative way. Then, the definition along with its influence of electronic effect, double layer effect and mass transport have been reviewed based on a mechanism point of view for the first time. To sum up the review, several current challenges and future prospects of pulsed electrolysis have provided for the future smart design of electrochemical process.

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Section: Historical Analysis Of Pulsed Electrolysis Via a Bibliometri...mentioning

confidence: 84%

A Bibliometric Analysis on Pulsed Electrolysis: Electronic Effect, Double Layer Effect, and Mass Transport

Wang,

Liu,

Liu

et al. 2023

Catalysts

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A Direct CO Polymer Electrolyte Membrane Fuel Cell

et al. 2006

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A Direct CO Polymer Electrolyte Membrane Fuel Cell

et al. 2006

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A good source of energy: The reformation of hydrocarbons generates CO as well as H2. Despite its high reducing activity, CO is not suitable as a fuel in polymer electrolyte membrane fuel cells (PEMFCs) because it is a strong poison for the Pt catalyst used as the anode. A new fuel cell has now been developed with a rhodium octaethylporphyrin ([Rh(oep)]) anode catalyst that uses neat CO as a fuel, and delivers high performance (see graph).

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Reduction of CO Content in Hydrogen Rich Fuel by CO Electrolytic Oxidation for Reformed Gas Fueled PEFCs

Cited by 10 publications

References 6 publications

A Bibliometric Analysis on Pulsed Electrolysis: Electronic Effect, Double Layer Effect, and Mass Transport

A Bibliometric Analysis on Pulsed Electrolysis: Electronic Effect, Double Layer Effect, and Mass Transport

A Direct CO Polymer Electrolyte Membrane Fuel Cell

A Direct CO Polymer Electrolyte Membrane Fuel Cell

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