Reduction kinetics of neodymium chloride in the equimolar NaCl–KCl melt

Chernova, O. V.; Zhukovin, S. V.; Bushuev, A. N.

doi:10.1134/s0036029515080042

Russ. Metall.

2015

DOI: 10.1134/s0036029515080042

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Reduction kinetics of neodymium chloride in the equimolar NaCl–KCl melt

O. V. Chernova

S. V. Zhukovin

A. N. Bushuev

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“…In Ref. 19 the kinetic parameters (transfer coefficient, heterogeneous charge transfer rate constants) of the NdCl 3 electroreduction in an equimolar NaCl-KCl melt were determined using chronopotentiometry and voltammetry methods.…”

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confidence: 99%

Electrochemistry of Neodymium in an Equimolar NaCl-KCl Melt without and with Addition of Fluoride Ions

Kuznetsov¹,

Popova²,

Stulov³

et al. 2023

J. Electrochem. Soc.

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The paper presents the results of neodymium electrochemical behavior in chloride and chloride-fluoride melts. It was shown that the process of neodymium electroreduction in the NaCl-KCl-NdCl3 melt proceeds in two stages. By diagnostic criteria of voltammetry it was established that the discharge process of Nd(III) to Nd(II) at a sweep rate in the range of 0.6 ≤  ≤ 1.0 V s-1 is not complicated by disproportionation reaction. In this study diffusion coefficients, activation energy of diffusion for Nd(III) chloride complexes and standard rate constants of charge transfer for the Nd(III)/Nd(II) redox couple in the NaCl-KCl melt were determined. The nature of the working electrode on the standard rate constants of charge transfer for the Nd(III)/Nd(II) redox couple has been studied by cyclic voltammetry and electrochemical impedance spectroscopy. The formal redox potentials E*Nd(III)/Nd(II) in the NaCl-KCl melt were obtained from the cyclic voltammetry data. It was shown that the addition of fluorine anions into the NaCl-KCl-NdCl3 melt leads to stabilization of the higher oxidation state of neodymium in chloride-fluoride melts and the intermediate oxidation state Nd(II) does not exist in these melts.

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mentioning

confidence: 99%

Electrochemistry of Neodymium in an Equimolar NaCl-KCl Melt without and with Addition of Fluoride Ions

Kuznetsov¹,

Popova²,

Stulov³

et al. 2023

J. Electrochem. Soc.

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Low-Level Laser Therapy for Herpesvirus Infections: A Narrative Literature Review

Moskvin

2021

J Lasers Med Sci

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Introduction: Herpesvirus infection has a variety of clinical forms and is extremely widespread in the world while existing treatment methods are not always quite effective. The search for new treatment modalities is a relevant problem and numerous studies show the therapeutic effect of low-level laser therapy (LLLT) on different herpesvirus types. Methods: The mechanisms of laser light action and the impact of LLLT on the pathological pathways of herpes infections are described. A narrative review of the relevant papers is conducted. Results: The reviewed studies confirm that LLLT is a potential prospective treatment method for patients infected with the herpesvirus. However, it is necessary to improve the methodology and optimize the combination of laser action with antiviral medications. Conclusion: The review shows that it is most effective to combine laser impact on skin lesions with the application of topical antiviral gels or creams, additionally using a combined procedure of laser ultraviolet blood illumination (LUVBI, 365-405 nm) + intravenous laser blood irradiation (ILBI, 525 nm).

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Reduction kinetics of neodymium chloride in the equimolar NaCl–KCl melt

Cited by 2 publications

References 1 publication

Electrochemistry of Neodymium in an Equimolar NaCl-KCl Melt without and with Addition of Fluoride Ions

Electrochemistry of Neodymium in an Equimolar NaCl-KCl Melt without and with Addition of Fluoride Ions

Low-Level Laser Therapy for Herpesvirus Infections: A Narrative Literature Review

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