2015
DOI: 10.3906/kim-1401-40
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Reduction behavior of fenoxaprop-p-ethyl and its voltammetric determination

Abstract: Abstract:The reduction behavior of fenoxaprop-p-ethyl (FNX) was studied on a hanging mercury drop electrode. FNX showed 2 reduction peaks at about -0.7 V and at about -0.9 V versus Ag/AgCl/3.0 M KCl in Britton-Robinson buffer at pH 4.8. Both reductions were irreversible and adsorption was effective. The reduction peaks were assigned to the reduction of C=N to CH-NH and the reduction of C=O to CH-OH. Square-wave voltammetry has been proposed and

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Cited by 3 publications
(1 citation statement)
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“…According to literature, the slope of logarithm of peak current versus logarithm of scan rate approaches to unity when mechanism is controlled by adsorption whereas diffusion controlled mechanisms have the slope value of 0.5 . When obtained slope value for this graph at Figure B.b is considered, the slope value of 0.16 neither exactly corresponds to adsorption or diffusion controlled process.…”
Section: Characterization Of Au‐film Electrodementioning
confidence: 99%
“…According to literature, the slope of logarithm of peak current versus logarithm of scan rate approaches to unity when mechanism is controlled by adsorption whereas diffusion controlled mechanisms have the slope value of 0.5 . When obtained slope value for this graph at Figure B.b is considered, the slope value of 0.16 neither exactly corresponds to adsorption or diffusion controlled process.…”
Section: Characterization Of Au‐film Electrodementioning
confidence: 99%