Polyimide
aerogels (PIAs) are thermally insulating materials
that
possess various advantages, such as exceptionally high temperature
resistance and low thermal conductivity, which make them great potential
candidate materials to be applied in the area of thermal protection.
However, under harsh mechanical stresses, the macro- and microscopic
structural stability of PIAs may be compromised due to shrinkage/collapse,
leading to performance degradation. Herein, we propose a homogeneous
organic/inorganic hybrid formation strategy for constructing nanoporous
polyimide/silica aerogels (PIAs-A) with exceptional mechanical strength
and ultralow thermal conductivity. The results obtained indicate that
PIAs-A have an optimal three-dimensional nanoporous network structure
with a pore size distribution mainly within the range of 10–20
nm. Monitoring the temperature evolution of the material’s
cold surface showed that it remained at a low temperature of 37.5
°C even when the material was placed against a hot surface of
150 °C. The residual mechanical strengths of the aerogels remained
at a superior level (with strength degradation being less than 9%)
after exposure to ultralow and high-temperature atmospheres. Furthermore,
compressive stress values at 3% strain exceeded previously reported
values for PIAs by 625 and 733% at −50 and 100 °C, respectively.
Meanwhile, our aerogels displayed flame resistance even when exposed
to a heat source of approximately 1200 °C, possessed favorable
hydrophobic properties, and maintained dimensional stability up to
504 °C. The robust mechanical and thermal insulation properties
of PIAs-A make them a promising substitute material for thermal superinsulation
in aircraft.