To extend the service life and ensure the operability of oil-filled transformer equipment, the attention is paid to the development of methods for monitoring the state of oil-barrier insulation. When monitoring the technical condition of transformer oil, the class of liquid purity is determined depending on the rated voltage of the equipment. However, the influence of the parameters of mechanical impurities on the breakdown voltage is not taken into account, thereby lowering the requirements for the quality of oil barrier insulation. This makes it relevant to study the influence of the size distribution of impurity particles on the electric strength of the internal insulation of power transformers and determine the parameters of particles of mechanical impurities to justify the underestimation of the quality indicators of transformer oil in operation. Methods of mathematical statistics were employed using the Gnedenko-Weibull distribution based on the standard values of liquid purity classes. To determine the maximum and minimum voltages, the standard values of the average breakdown voltages and the results of operational tests of transformer oil in a standard spark gap were used. The relation between the particle size of mechanical impurities and the breakdown voltage of transformer oil has been established. The particle size distribution of impurities has been obtained for 12 and 13 classes of liquid purity for power transformers with a voltage of 110–750 kV. The particle size range that defines the maximum and minimum breakdown voltages has been determined, and the values of limit concentrations of mechanical particles have been established. The obtained parameters of impurity particles which determine the maximum and minimum breakdown voltages of the operating oils can be used to evaluate the technical condition when diagnosing the internal insulation of power transformers in order to increase their operational reliability, as well as to adjust the regulatory requirements for the quality of operational transformer oil according to the content of mechanical impurities.