Redox-active 2D porous organic polymers for high-performance supercapacitor

Hu, Daping; Jia, Yuhang; Yang, Sui; Huang, Fuyao; Dong, Yuman; Du, Pengcheng

doi:10.1016/j.jiec.2023.03.049

Cited by 7 publications

(3 citation statements)

References 59 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…CNT@TFA-COF a facile one-pot method 338 F g À 1 at 1 A g À 1 86 % (7000, 5 A g À 1 ) / three [168] COP-2 solvothermal heating condition 404 F g À 1 at 0.5 A g À 1 100 % (50000) 14, 1848 three [169] Tp-AT-POP solvothermal Schiffbase condensation 348.3 F g À 1 at 0.5 A g À 1 71 % (5000) 26.02, 2120 three [170] HM-COF solvothermal reaction 145 F g À 1 at 0.5 A g À 1 84.6 % (30000, 2 A g À 1 ) / three [163] DBT-MA-COF solvothermal reaction 407 F g À 1 at 1 A g À 1 85 % (20000, 5 A g À 1 ) 32.1, 800 three [78] TAPT-2,3-NA(OH) 2…”

Section: Electrode Systemmentioning

confidence: 99%

Redox‐Active Organic Electrode Materials for Supercapacitors

Ding,

Xiao,

et al. 2023

Batteries & Supercaps

View full text Add to dashboard Cite

Due to their prominent power density, supercapacitors carve out a niche among all the energy storage systems. However, it is also well known that the energy density of supercapacitors takes no advantage over lithium‐ion batteries, the current star energy storage device. Therefore, substantial efforts have been paid to improving the energy density of supercapacitors not at the expense of its power density. To develop electrode with high capacitance is a direct and efficient way to increase the energy storage capability of supercapacitors. Organics whose molecular structure can be diversely designed to achieve high pseudocapacitance arising from redox active units in their backbone are good candidates as electrode materials for supercapacitors. Herein, this review summarizes recent progress of redox‐active organic electrode materials for supercapacitors and their pseudocapacitive energy storge mechanisms based on different organic functional groups. From the aspects of their preparation approaches, molecular design and the resultant electrochemical performances, the focus is to probe the relationship between the energy storage mechanisms and the molecular structure of redox‐active units and provide some insights for the further development of organic supercapacitor electrodes.

show abstract

Section: Electrode Systemmentioning

confidence: 99%

Redox‐Active Organic Electrode Materials for Supercapacitors

Ding,

Xiao,

et al. 2023

Batteries & Supercaps

View full text Add to dashboard Cite

show abstract

“…Porous organic polymers (POPs) are a class of emerging multifunctional materials that show excellent properties in a variety of applications, [1][2][3] such as gas separation, [4,5] catalysis, [6,7] lithium-ion batteries, [8,9] supercapacitors, [10,11] and in electrochromism. [12,13] However, most POPs have neutral backbone structures which can limit their structural and functional versatility.…”

Section: Introductionmentioning

confidence: 99%

Electrochemical Formation of Ionic Porous Organic Polymers Based on Viologen for Electrochromic Applications

Shao,

Dong,

et al. 2024

Macromol. Rapid Commun.

View full text Add to dashboard Cite

The systematic study of two ionic porous organic polymers (iPOPs) based on viologens and their first applications in the electrochromic field are reported. The viologen‐based iPOPs were synthesized by electrochemical polymerization with cyano groups, providing a simple and controllable method for iPOPs which solves the film preparation problems common to viologens. After characterisation of these iPOPs a detailed study of their electrochromic properties was conducted. The iPOPs films based on viologens structure exhibit excellent electrochromic properties. In addition, the resulting iPOPs films show highly sensitivity to electrolyte ions of different sizes in the redox process. Electrochemical and electrochromic data of the iPOPs explain this phenomenon in detail. These results demonstrate that iPOPs of this type are ideal candidates as electrochromic materials due to their inherent porous structures and ion‐rich properties.This article is protected by copyright. All rights reserved

show abstract

“…One of the key advantages of COPs for supercapacitor applications is their high surface area, which can be tuned by adjusting the size and shape of the monomers used to synthesize the polymer. [46][47][48] The signicant surface area offered by these materials provides numerous active sites for electrochemical reactions to occur which can enhance the energy storage capacity of the supercapacitor. 49,50 Additionally, COPs can be easily synthesized using simple and cost-effective methods, which makes them attractive for largescale production.…”

Section: Introductionmentioning

confidence: 99%