Redetermination of Tetrakis(methylammonium) Hexachloroindate Chloride

Rothammel, W.; Spengler, R.; Burzlaff, H.; Jarraya, S.; Salah, A. Ben

doi:10.1107/s0108270198099284

Cited by 3 publications

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“…In [InCl 6 ] 3-, the indium center is coorinated by six Cl atoms, resulting in a slightly distorted octahedral geometry. The In-Cl bond distances are in the range of 2.5024 (5)-2.5114 (7) Å, which is consistent with other hexachloro-indium compounds (Rothammel et al, 1998). In [Co(dien) 2 ] 3+ , the cobalt center also displays a slightly distorted octahedral geometry and is bonded to six N atoms of two diethylenetriamines with the Co-N distances of 1.967 (2)-1.9684 (15) Å.…”

Section: Structure Reports Onlinesupporting

confidence: 75%

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Bis(diethylenetriamine)cobalt(III) hexachloridoindate(III)

Chen

Zhang

et al. 2011

Acta Cryst E

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The title compound, [Co(C4H13N3)2][InCl6], was synthesized under hydrothermal conditions. In the cation, the Co—N bond lengths lie in the range 1.967 (2)–1.9684 (15) Å. In the anion, the InIII atom is coordinated by six Cl atoms resulting in a slightly distorted octahedral geometry. Both metal atoms are located on special positions of site symmetry 2/m. Furthermore, one Cl atom and one N atom are located on a mirror plane. N—H⋯Cl hydrogen bonds between cations and anions consolidate the crystal packing.

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Section: Structure Reports Onlinesupporting

confidence: 75%

“…For the introduction of chiral metal complexes into coordination polymers, see: Pan et al (2010aPan et al ( ,b, 2011Tong & Pan (2011). For In-Cl bond lengths in other hexachloridoindium compounds, see: Rothammel et al (1998).…”

Section: Related Literaturementioning

confidence: 98%

Bis(diethylenetriamine)cobalt(III) hexachloridoindate(III)

Chen

Zhang

et al. 2011

Acta Cryst E

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“…Thus, it is an effective way that bring small ammonium cations in crystal structure for designing phase transition. At the same time, according to relevant literatures, we found that the In 3+ ion can coordinate with different numbers of halogen anions to form different indium halide anions, such as InX 4 – , InX 5 2– , and InX 6 3– . Polish professor R. Jakubas reported the phase transitions and structures of [(CH 3 ) 4 N]InBr 4 and [(C 2 H 5 ) 4 N]InBr 4 , the results indicate that the order‐disorder transition of organic ammonium is the main factor of phase transition.…”

Section: Introductionmentioning

confidence: 74%

“…, and InX 6 3-. [27][28][29] Polish professor R. Jakubas reported the phase transitions and structures of [(CH 3 ) 4 N]InBr 4 and [(C 2 H 5 ) 4 N]InBr 4 , the results indicate that the order-disorder transition of organic ammonium is the main factor of phase transition. In addition, Professor D.G.…”

Section: -mentioning

confidence: 99%

Switchable Dielectric Behavior and Order‐Disorder Phase Transition in a New Organic‐Inorganic Hybrid Compound: (CH₃NH₃)₄[InCl₆]Cl

Xin

et al. 2020

Eur J Inorg Chem

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A new organic‐inorganic phase transition material (CH3NH3)4[InCl6]Cl (1), has been successfully synthesized and characterized. The compound undergoes a reversible first‐order phase transition at Curie temperature Tc=284 K, accompanied with a wide hysteresis of 12 K, which investigated by differential scanning calorimetry (DSC). The temperature dependence of the dielectric permittivity discloses an obvious step‐like dielectric anomaly. Single crystal X‐ray diffraction reveals that the order‐disorder transition of the [InCl6]3– anion and the methylammonium cation were the main factor drove the phase transition from high temperature phase with the space group P2/m to low temperature phase with the space group P2/n. This finding indicates that In‐based organic–inorganic hybrids compounds can be used to build phase transition materials, which broaden the way for exploring dielectric switching materials.

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“…For related compounds, see Pan et al (2005Pan et al ( , 2008Pan et al ( , 2010aPan et al ( ,b, 2011; Rothammel et al (1998); Stalder & Wilkinson (1997); Tong & Pan (2011); Wang et al (2003a,b).…”

Section: Related Literaturementioning

confidence: 99%

Tris(2,2′-bi-1H-imidazole-κ²N³,N^3′)cobalt(II) hydrogen phosphate

Liang

Wang

et al. 2011

Acta Cryst E

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The title compound, [Co(C6H6N4)3]HPO4, was synthesized under hydrothermal conditions. In the cation, the CoII atom is octahedrally coordinated by six N atoms from three 2,2′-bi-1H-imidazole ligands [Co—N bond lengths are in the range 2.084 (5)–2.133 (6) Å]. Intermolecular N—H⋯O hydrogen bonds form an extensive hydrogen-bonding network, which links cations and anions into a three-dimensional crystal structure.

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Redetermination of Tetrakis(methylammonium) Hexachloroindate Chloride

Cited by 3 publications

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Bis(diethylenetriamine)cobalt(III) hexachloridoindate(III)

Bis(diethylenetriamine)cobalt(III) hexachloridoindate(III)

Switchable Dielectric Behavior and Order‐Disorder Phase Transition in a New Organic‐Inorganic Hybrid Compound: (CH₃NH₃)₄[InCl₆]Cl

Tris(2,2′-bi-1H-imidazole-κ²N³,N^3′)cobalt(II) hydrogen phosphate

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Redetermination of Tetrakis(methylammonium) Hexachloroindate Chloride

Cited by 3 publications

References 0 publications

Bis(diethylenetriamine)cobalt(III) hexachloridoindate(III)

Bis(diethylenetriamine)cobalt(III) hexachloridoindate(III)

Switchable Dielectric Behavior and Order‐Disorder Phase Transition in a New Organic‐Inorganic Hybrid Compound: (CH3NH3)4[InCl6]Cl

Tris(2,2′-bi-1H-imidazole-κ2N3,N3′)cobalt(II) hydrogen phosphate

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Product

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Switchable Dielectric Behavior and Order‐Disorder Phase Transition in a New Organic‐Inorganic Hybrid Compound: (CH₃NH₃)₄[InCl₆]Cl

Tris(2,2′-bi-1H-imidazole-κ²N³,N^3′)cobalt(II) hydrogen phosphate