Recovery of Spent Sulphuric Acid by Diffusion Dialysis Using a Spiral Wound Module

Merkel, Arthur; Čopák, Ladislav; Dvořák, Lukáš; Голубенко, Д. В.; Seda, Libor

doi:10.3390/ijms222111819

Cited by 12 publications

(12 citation statements)

References 33 publications

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“…AEMs (anion exchange membranes) and CEMs (cation exchange membranes) are two major categories of IEMs. AEMs have lately attracted considerable attention because they can effectively retrieve acid wastes from various industries such as mining, metal manufacturing, painting, and agriculture [21][22][23][24].…”

Section: Introductionmentioning

confidence: 99%

Synthesis of Porous BPPO-Based Anion Exchange Membranes for Acid Recovery via Diffusion Dialysis

et al. 2022

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Diffusion dialysis (DD) is an anion exchange membrane-based functional separation process used for acid recovery. TMA (trimethylamine) and BPPO (brominated poly (2,6-dimethyl-1,4-phenylene oxide) were utilized in this manuscript to formulate AEMs (anion exchange membranes) for DD (diffusion dialysis) using the phase-inversion technique. FTIR (Fourier transfer infrared) analysis, proton NMR spectroscopy, morphology, IEC (ion exchange capacity), LER (linear expansion ratio), CR (fixed group concentration), WR (water uptake/adsorption), water contact angle, chemical, and thermal stability, were all used to evaluate the prepared membranes. The effect of TMA content within the membrane matrix on acid recovery was also briefly discussed. It was reported that porous AEMs have a WR of 149.6% to 233.8%, IEC (ion exchange capacity) of 0.71 to 1.43 mmol/g, CR (fixed group concentration) that ranged from 0.0046 mol/L to 0.0056 mol/L, LER of 3.88% to 9.23%, and a water contact angle of 33.10° to 78.58°. The UH (acid dialysis coefficients) for designed porous membranes were found to be 0.0043 to 0.012 m/h, with separation factors (S) ranging from 13.14 to 32.87 at the temperature of 25 °C. These observations are comparable to those found in the DF-120B commercial membrane with UH of 0.004 m/h and S of 24.3 m/h at the same temperature (25 °C). This porous membranes proposed in this paper are excellent choices for acid recovery through the diffusion dialysis process.

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Section: Introductionmentioning

confidence: 99%

Synthesis of Porous BPPO-Based Anion Exchange Membranes for Acid Recovery via Diffusion Dialysis

et al. 2022

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“…The DD process in a continuous regime was characterized by equations of acid recovery ratio, metal ion rejection, and purities of the obtained streams, which were proposed in a previous work [ 17 ].…”

Section: Methodsmentioning

confidence: 99%

“…Previously, we conducted a study on the dependence of volumetric flow and feed temperature on the performance of the same spiral-wound module for the recovery of free sulfuric acid from 5.4% wt. sulfuric acid solution containing 284 ppm of Fe 2+ and 50 ppm of Cu 2+ [ 17 ]. The results indicated that an increase in the volumetric flow rate of water increased free acid yield from 88% to 93%, but decreased Cu 2+ and Fe 2+ ion rejection from 95% to 90% and from 91% to 86%, respectively.…”

Section: Introductionmentioning

confidence: 99%

Recovery of Hydrochloric Acid from Industrial Wastewater by Diffusion Dialysis Using a Spiral-Wound Module

Merkel

Čopák

Голубенко

et al. 2022

IJMS

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In the present study, the possibility of using a spiral-wound diffusion dialysis module was studied for the separation of hydrochloric acid and Zn2+, Ni2+, Cr3+, and Fe2+ salts. Diffusion dialysis recovered 68% of free HCl from the spent pickling solution contaminated with heavy-metal-ion salts. A higher volumetric flowrate of the stripping medium recovered a more significant portion of free acid, namely, 77%. Transition metals (Fe, Ni, Cr) apart from Zn were rejected by >85%. Low retention of Zn (35%) relates to the diffusion of negatively charged chloro complexes through the anion-exchange membrane. The mechanical and transport properties of dialysis FAD-PET membrane under accelerated degradation conditions was investigated. Long-term tests coupled with the economic study have verified that diffusion dialysis is a suitable method for the treatment of spent acids, the salts of which are well soluble in water. Calculations predict significant annual OPEX savings, approximately up to 58%, favouring diffusion dialysis for implementation into wastewater management.

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“…In recent years, there have been several studies on the regeneration of waste solutions by diffusion dialysis [ 3 , 4 , 5 , 6 , 7 , 8 , 9 , 10 , 11 , 12 , 13 , 14 , 15 , 16 , 17 , 18 , 19 ]. Lan et al [ 3 ] published results on the recovery of HNO 3 from acid effluents discharged by an electrodialysis plant.…”

Section: Introductionmentioning

confidence: 99%

Treatment of Spent Pickling Solutions by Diffusion Dialysis Using Anion-Exchange Membrane Neosepta-AFN

Bendová

Dušek

2022

Membranes

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This article presents the possibility of using diffusion dialysis for processing spent pickling solution from pickling stainless steels with a mixture of nitric acid and hydrofluoric acid. A counter-current two-compartment dialyzer equipped with an anion-exchange membrane Neosepta-AFN was used to study and compare the diffusion dialysis of model mixture of hydrofluoric acid and ferric nitrate and a real spent pickling solution. The separation efficiency was characterized by the acid recovery yield, the rejection coefficient of the metals, the permeability coefficient of the membrane, and the separation factor. These characteristics were calculated from the data obtained at steady state. For the real spent pickling solution tested, the permeability values of nitrates 1.7 × 10−6 m s−1, fluorides 0.4 × 10−6 m s−1, and ferric ions 1.1 × 10−7 m s−1 were achieved. The separation factor for nitrates/ferric ions was 15.7 and 3.6 for fluorides/ferric ions. Furthermore, the dependencies of recovery yield and rejection for different concentrations of hydrofluoric acid and ferric nitrate were determined.

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Recovery of Spent Sulphuric Acid by Diffusion Dialysis Using a Spiral Wound Module

Cited by 12 publications

References 33 publications

Synthesis of Porous BPPO-Based Anion Exchange Membranes for Acid Recovery via Diffusion Dialysis

Synthesis of Porous BPPO-Based Anion Exchange Membranes for Acid Recovery via Diffusion Dialysis

Recovery of Hydrochloric Acid from Industrial Wastewater by Diffusion Dialysis Using a Spiral-Wound Module

Treatment of Spent Pickling Solutions by Diffusion Dialysis Using Anion-Exchange Membrane Neosepta-AFN

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