Recovery of Oil by Displacements With Water-Solvent Mixtures

Abstract

Published in Petroleum Transactions, Volume 219, 1960, pages 293–300. Abstract This paper presents the results of a laboratory investigation of the efficiency of water-solvent mixtures in recovery of oil. These mixtures may have the high displacement efficiencies characteristic of solvent floods and the high sweep efficiencies characteristic of water floods. Thus, the water-solvent process may increase the number of reservoirs in which a miscible-type displacement can be used profitably. The experiments on the use of water-solvent mixtures for recovery of oil were conducted to find the general applicability of the process. These studies demonstrated that, in flowing through sands, water and solvent segregated into a solvent layer on the top and a water layer on the bottom rather than flowing through the sands as a uniform mixture. Calculations based on the simultaneous flow of the water and solvent in layers were used to predict the effective mobility of the mixtures and the optimum operation of the process in steeply dipping, homogeneous reservoirs. As most reservoirs are not suited for the operation of the process under ideal conditions, experimental studies were conducted with sand-packed models scaled to represent more realistic reservoirs. These studies included the effects on recovery of oil of rate of injection, viscosity of oil, variations of permeability within a formation and variations in water-solvent ratio. For the range of conditions studied, higher recoveries of oil were obtained with water-solvent mixtures than with water or practical volumes of solvent alone. Introduction A group of intriguing-because of their great possibilities - new oil recovery methods at the disposal of the petroleum engineer are the miscible displacement processes. These processes (high-pressure gas drive, enriched-gas drive and LPG bank driven by methane) displace all of the oil from the portions of the reservoir swept by the injection fluid. The key question confronting the engineer applying one of these techniques to a particular reservoir is, "What fraction of the reservoir can be swept by injection of a practical volume of solvent?".

Reactive miscible displacement of light oil in porous media

“…When injection occurs in deep reservoirs, the injected fluid can become totally miscible with the oil due to high reservoir pressure (typically above 100 bars). In this case, the recovery efficiency depends on a series of factors [12,13], such as longitudinal dispersion, channeling and difference in the viscosities, which can destabilize the displacement process. If fingers are formed during the displacement, early breakthrough of oxygen can occur, resulting in poor recovery and a safety issue.…”