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Natural durability is one of the most rated features in wood end-use applications. In fact, several precious native tropical wood species produce timber of high natural durability, which is also related to long service life even for the highest hazard classes. However, selective logging is driving the existing volume of this group of species to near extinction. The remainder of the alternative species produces perishable timbers, which require synthetic chemical protection to prolong their service life but with detrimental effects on humans and the environment. Therefore, transferable durability has emerged as an alternative to gradually substitute traditional wood preservatives. From this approach, extractives from naturally durable wood species are removed and transferred to the non-durable wood species as an alternative environmental-friendly option for wood protection. Indeed, extractives from durable wood species have proven to have a deterrent effect on fungi, bacteria and termites and could be used to protect perishable wood species. Thus, this review aims to assess the prospects of developing environmentally friendly wood preservatives based on extractives sourced from highly natural, durable wood species to treat and add value to the group of perishable timbers. A step-wise analysis offers insights and challenges on (i) potential sources of extractives; (ii) effective extraction methods; (iii) extractive-based preservative formulation; and (iv) effective treatment methods for better preservative fixation for better wood protection. Accounts about the way forward for the development of extractive-based wood preservatives are also presented.
Natural durability is one of the most rated features in wood end-use applications. In fact, several precious native tropical wood species produce timber of high natural durability, which is also related to long service life even for the highest hazard classes. However, selective logging is driving the existing volume of this group of species to near extinction. The remainder of the alternative species produces perishable timbers, which require synthetic chemical protection to prolong their service life but with detrimental effects on humans and the environment. Therefore, transferable durability has emerged as an alternative to gradually substitute traditional wood preservatives. From this approach, extractives from naturally durable wood species are removed and transferred to the non-durable wood species as an alternative environmental-friendly option for wood protection. Indeed, extractives from durable wood species have proven to have a deterrent effect on fungi, bacteria and termites and could be used to protect perishable wood species. Thus, this review aims to assess the prospects of developing environmentally friendly wood preservatives based on extractives sourced from highly natural, durable wood species to treat and add value to the group of perishable timbers. A step-wise analysis offers insights and challenges on (i) potential sources of extractives; (ii) effective extraction methods; (iii) extractive-based preservative formulation; and (iv) effective treatment methods for better preservative fixation for better wood protection. Accounts about the way forward for the development of extractive-based wood preservatives are also presented.
Coffee, as one of the most consumed beverages, generates a wide variety of waste materials that can be used as biofuels and bio-products. Conventional pyrolysis can be used in rural areas, improving the circular bioeconomy of these places. In this work, the characterization and slow pyrolysis of specialty coffee residues, coffee silverskin (CSS), and spent coffee (SC) were conducted at temperatures from 300 to 600 °C. Physico-chemical and thermal analysis were carried out. In addition, the quantification of individual compounds as acetic, formic, and levulinic acids, caffeine, and other minor compounds was performed. The results indicate the differences between both waste materials in the obtained pyrolysis fractions. The biochar fraction for SC is lower at all temperatures and the liquid fraction higher, reaching maximum values of 62 wt.% in the liquid at 600 °C compared to 47% in CSS. The higher yield in the liquid fraction of SC corresponds to the higher contents of hemicellulose and extractives and the lower ash content. The calculated calorific value for the pyrolysis solid fractions reaches 21.93 MJ/kg in CSS and 26.45 MJ/kg in SC. Finally, biorefinery options of major components of the liquid fraction were also presented.
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