Emerging functional room-temperature
liquid metals generally include
gallium-based and bismuth-based alloys. Their excellent electrical
conductivity, thermal conductivity, flexibility, fluidity, and reflectivity
can enable their application in many fields. However, there are quite
a few problems that need to be solved before their application. For
example, liquid metals are often difficult to adhere and diffuse on
solid substrates due to their high surface tension and fluidity, which
hinders the application and promotion. Herein, we report a method
to develop multiphase soft metals from gallium- and bismuth-based
alloys. Particularly, room-temperature multiphase soft metals of GaBiInSn
alloys developed from Ga67In20.5Sn12.5 and Bi33.1In51.3Sn15.6 alloys via
compositing, mixing, and heating treatment are first reported, which
include the solid phase, liquid phase, and paste phase, respectively.
The free metal alloy grains are dispersed in GaBiInSn alloys and transition
constantly among different phases. More importantly, the structure,
size, density, and other characteristics of free metal alloy grains
can be modified by adjusting the mass ratio of each component. The
surface morphology, structure, wettability, adhesion, work function,
and photoelectric characteristics of multiphase soft metals can be
controlled and optimized by controlling phase transition. As a result,
the wettability of the obtained Ga50.25Bi8.28In28.2Sn13.27 is obviously improved (the contact
angle decreased from 118.5° to 94°), with a high work function
(4.75 eV), high reflectivity (78.14%), low electrical resistivity
(2.94 × 10–7 Ω m). Meanwhile, several
typical applications of the multiphase materials were demonstrated.
The results of this work will offer a promising strategy to directly
prepare liquid metal flexible electrodes on PI, PET, and silk, and
also, the stability can be kept well under large deformation and curling
conditions.