Recommendations on reporting electrode potentials in nonaqueous solvents (Recommendations 1983)

Gritzner, G.; Kůta, J.

doi:10.1351/pac198456040461

Cited by 1,288 publications

(852 citation statements)

References 2 publications

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“…In order to evaluate the stability of the Pt wire as quasi-RE we test its behaviour with respect to the Ferrocene/ Ferrocenium redox couple (5 mM solution) in aerated EdMPNTf2N [10]. The CVs obtained on glassy carbon electrode (+3 mm) are comparable to the curves reported in the literature for similar ILs [11][12][13] characterized by an almost reversible one-electron oxidation process.…”

Section: Stability Of Resupporting

confidence: 55%

Ionic liquids as diathermic fluids for solar trough collectors’ technology: A corrosion study

Perissi

Bardi

Caporali

et al. 2008

Proceedings of ISES World Congress 2007 (Vol. I – Vol. V)

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The AISI 304 and AISI 1018 steels (frequently used in solar collectors' plants) in contact with four different ionic liquids (ILs) suitable as diathermic fluids, were studied. Immersion tests were performed at 220 1C (the working temperature in such plants) for 10 days. The corrosion morphologies of the steels were investigated by scanning electron microscopy coupled with energy dispersive X-ray (EDX) microanalysis and the content of metals in the solution were detected via ICP-OES. The tests showed that the most performing IL is the ethyl-dimethyl-propyl-ammonium-bis(trifluoromethylsulphonyl)imide. The corrosion properties of the two alloys in contact with such IL were investigated by means of Tafel plots and resistance polarization at room temperature in open-to-air vessels. r

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Section: Stability Of Resupporting

confidence: 55%

Ionic liquids as diathermic fluids for solar trough collectors’ technology: A corrosion study

Perissi

Bardi

Caporali

et al. 2008

Proceedings of ISES World Congress 2007 (Vol. I – Vol. V)

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“…Experimentally potentials were referenced against a Ag/Ag + reference electrode but the results are presented referenced against the FcH/FcH + couple (E 0 ' = 0.0 mV) as required by IUPAC [30]. When decamethylferrocene was used as an internal standard, the experimentally measured potential was converted in to E vs FcH/FcH + by addition of -0.61 V [31].…”

Section: Electrochemistrymentioning

confidence: 99%

(Spectro)electrochemical investigations on (ferrocenyl)thiophenes modified by tungsten Fischer carbenes

Westhuizen¹,

Speck²,

Korb³

et al. 2014

Journal of Organometallic Chemistry

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A series of thiophene tungsten Fischer carbene complexes of type [(CO) 5 W=C(OMe)R] (1, R = 2-Th; 3, R = fcthFc) and [(CO) 5 W=C(OMe)-R'-(OMe)C=W(CO) 5 ] (2, R' = th; 5, R' = fcthfc) was synthesized for investigating low energy charge transfer interactions between the carbene substituents and the transition metal carbonyl fragment incorporating the thiophene heterocyclic system (Th = Thienyl; th = 2,5-thiendiyl; Fc = ferrocenyl; fc = 1,1'-ferrocenediyl).Electrochemical investigations were carried out on these complexes to get a closer insight into the electronic properties of 1, 2, 4 and 5. They reveal reversible one-electron redox events for the 2 ferrocenyl moieties. Moreover, typical electrode reactions could be found for the carbene reductions itself and for the tungsten carbonyl oxidation processes. However, for the thiophene complex 2 two well-separated one-electron reduction events were observed. During the UV-Vis-NIR spectroelectrochemical investigations typical low energy absorptions for the mixed-valent α,α'-diferrocenyl thiophene increment were found, as well as high energy NIR absorptions, which were attributed to metal-metal charge transfer transition between the tungsten carbonyl increment and the ferrocenyl units in the corresponding species. Further infrared spectroelectrochemical studies reveal that the electronic interactions in the corresponding cationic species can be described with weakly coupled class II systems according to Robin and Day.

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“…The working cell included a Glassy Carbon GC disk embedded in Teflon Ò (Amel, surface 0.071 cm 2 ) as the working electrode, the polishing procedure consisting in surface treatment with alumina powder (Metrohm) on wet 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 8 (SCE, Amel) as the reference electrode. According to IUPAC recommendations the data have been referred to the Fc + /Fc redox couple (ferricinium/ferrocene), having a formal potential of 0.390 V vs our operating reference electrode [61]. The ohmic potential drop was compensated by the positive feedback technique [62].…”

Section: Electrochemistrymentioning

confidence: 99%

Ternary thiophene–X–thiophene semiconductor building blocks (X=fluorene, carbazole, phenothiazine): Modulating electronic properties and electropolymerization ability by tuning the X core

Tacca

Pò

Caldararo

et al. 2011

Electrochimica Acta

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To achieve rationalization criteria for target-oriented molecular design of Th-X-Th (Th = thiophene) semiconductor building blocks, we have carried out an extensive investigation on the effects of the X core (X = fluorene, carbazole or phenothiazine) on the electronic properties and polymerization ability of Th-X-Th monomers and on the electronic and structural properties of the corresponding periodic conducting polymers -(Th-X-Th) n -, obtained by electropolymerization and, for

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Recommendations on reporting electrode potentials in nonaqueous solvents (Recommendations 1983)

Abstract: Abstract

Cited by 1,288 publications

References 2 publications

Ionic liquids as diathermic fluids for solar trough collectors’ technology: A corrosion study

Ionic liquids as diathermic fluids for solar trough collectors’ technology: A corrosion study

(Spectro)electrochemical investigations on (ferrocenyl)thiophenes modified by tungsten Fischer carbenes

Ternary thiophene–X–thiophene semiconductor building blocks (X=fluorene, carbazole, phenothiazine): Modulating electronic properties and electropolymerization ability by tuning the X core

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