A supersonic argon and argon-hydrogen (3-5{%}) plasma jet generated
by an induction plasma torch is studied by means of the methods of optical
emission spectroscopy. The torch was operated at the input power of 20 kW
and near atmospheric pressure. The supersonic jet with a periodic structure
of expansion and compression zones is created by expanding the plasma
through the Laval nozzle into a chamber maintained at the pressure around
1.8 kPa. Atomic argon lines with the upper level energies ranging from 13.3
to 15.5 eV, continuum emission and Hβ line profile are used to
evaluate plasma parameters such as temperature and electron number density.
Analysis based on the Boltzmann diagram, line-to-continuum ratio, population
of continuum extrapolated level and Stark broadening reveals various stages
of departure from thermodynamic equilibrium in the plasma flow. It is shown,
among others, that the temperature derived from Boltzmann diagram does not
follow the jet structure and reliable determination of electron temperature
is questionable. An addition of several percent of hydrogen results in a
significant quenching of populations of atomic states and nonequilibrium
behaviour of continuum radiation.