In this study, we attempted to examine the dewaterability performances of sludge after pH/KMnO 4 treatment, with the goal of understanding the dewaterability of strong oxidizers to waste activated sludge.With adjustment of pH, the impacts of different KMnO 4 dosing on sludge dewatering are investigated.It plays good dewatering performance after treated by pH/KMnO 4 ,which showed by capillary suction ti-mes (CST) decreased from 263.4s to 30.1s,and SRF fell by about 19.6%.The result perfomanced that the proteins and polysaccharides were signi cant decreased in tightly-bound EPS.Meanwhile,it was got that higher zeta potentials, and more obvious T 2 after treatment.According to the changes of sludge's physicochemical properties,and the variety of EPS,explained the mechanisms of improv-ed sludge dewatering under pH/KMnO 4 conditions. Under the strong oxidation, the structure surrounding the bound water is oxidized and the bound water is released, so the dewaterability of the sludge is improved.