Recent Trends in Triarylborane Chemistry: Diversification of Structures and Reactivity via meta-Substitution of the Aryl Groups
Yoichi Hoshimoto,
Mahiro Sakuraba
Abstract:This Short Review summarizes the synthesis and applications of triarylboranes (BAr3), including both homoleptic and heteroleptic species, with a focus on the modification of their electronic and structural properties via the introduction of meta-substituents with respect to the B atoms to their Ar groups. This approach constitutes a complementary alternative to conventional strategies for the design of BAr3, which are usually based on a modification of their ortho- and/or para-substituents. An initial analysis… Show more
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