To the colleagues from the research group, especially Ricardo Kramer, Emanoelle, Fábio and the technician Ricardo Gomes, for their assistance in the laboratory and for the coffees.To Ricardo Kramer, also for the partnership in the development of ideas and writing of papers.To all colleagues in the PGrCEM postgraduate program.To the secretariat of the postgraduate program PGRCEM, in particular to Victor Barioto.To my friends from Grenoble, Matheus, Igor, João, Vinicius and Gabriel for the hours of talking about science.To my friends Carla, Jéssica, Paula and Larissa, incredible and inspiring women.To the longtime friends Daniel, Rafael and Jorge, partners for all hours.To Mirella, for the support and companionship, crucial at the beginning of this work.To Suzano Papel e Celulose S.A for the supply of nanofibrilated cellulose.To CNPq for the doctoral fellowship granted (CNPq proc. 140249/2017-6) and CAPES for the sandwich doctoral fellowship granted (proc. 88887.371652/2019-00).Learning is the only thing the mind never exhausts, never fears and never regrets.