Recent synthetic strategies for the construction of functionalized carbazoles and their heterocyclic motifs enabled by Lewis acids

Kumar, Marappan Pradeep; G., Mahantesh; Amaladass, P.; Manikandan, Chitrarasu; Dhayalan, Vasudevan

doi:10.1039/d3ra06396h

RSC Adv.

2023

DOI: 10.1039/d3ra06396h

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Recent synthetic strategies for the construction of functionalized carbazoles and their heterocyclic motifs enabled by Lewis acids

Marappan Pradeep Kumar,

Mahantesh G.,

P. Amaladass

et al.

Abstract: This review article demonstrates recent advanced cascade annulation strategies for preparing highly functionalized carbazoles and their related polyaromatic heterocyclic compounds enabled by Lewis acid catalysts.

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2024

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Photocatalytic Unsymmetrical Diamination of Styrenes, Indoles, and Benzofurans Facilitated by Benzotriazolyl and Iminyl Radicals

Luo,

Ye,

Zheng

et al. 2024

Org. Lett.

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Utilizing energy transfer catalysis, this research employed the bifunctional reagents benzotriazole carboxylic acid oxime esters to simultaneously generate benzotriazole and imine radicals. The synthesis of two distinct C−N bonds in a single conversion is showcased through radical addition and radical− radical cross-coupling processes between benzotriazole carboxylic acid oxime ester and olefins. This process facilitates the intermolecular two-component unsymmetrical diamination reaction of olefins. Using this approach, more than 40 benzotriazolecontaining molecules were successfully synthesized using styrene, indole, and benzofuran as acceptors, with yields ranging from moderate to excellent.

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Photocatalytic Unsymmetrical Diamination of Styrenes, Indoles, and Benzofurans Facilitated by Benzotriazolyl and Iminyl Radicals

Luo,

Ye,

Zheng

et al. 2024

Org. Lett.

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show abstract

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Recent synthetic strategies for the construction of functionalized carbazoles and their heterocyclic motifs enabled by Lewis acids

Abstract: This review article demonstrates recent advanced cascade annulation strategies for preparing highly functionalized carbazoles and their related polyaromatic heterocyclic compounds enabled by Lewis acid catalysts.

Cited by 1 publication

References 194 publications

Photocatalytic Unsymmetrical Diamination of Styrenes, Indoles, and Benzofurans Facilitated by Benzotriazolyl and Iminyl Radicals

Photocatalytic Unsymmetrical Diamination of Styrenes, Indoles, and Benzofurans Facilitated by Benzotriazolyl and Iminyl Radicals

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