Abstract:The synthetic approaches to design hexanuclear Lanthanide-based single molecule magnets are demonstrated in detail. Extensive analysis of the reported hexanuclear systems provides vital insight for controlling the relaxation dynamics of Ln(III)-based SMMS. The assembly of hexanuclear lanthanide-based SMMs employing several ligands is summarized. Favorable structural units could be exploited as motifs in the formation of novel Ln(III)-based SMMs, slow magnetic relaxation feature being the principal focus for th… Show more
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