Recent Progress in Spinel Ferrite (MFe2O4) Chemiresistive Based Gas Sensors

Abstract

Gas-sensing technology has gained significant attention in recent years due to the increasing concern for environmental safety and human health caused by reactive gases. In particular, spinel ferrite (MFe2O4), a metal oxide semiconductor with a spinel structure, has emerged as a promising material for gas-sensing applications. This review article aims to provide an overview of the latest developments in spinel-ferrite-based gas sensors. It begins by discussing the gas-sensing mechanism of spinel ferrite sensors, which involves the interaction between the target gas molecules and the surface of the sensor material. The unique properties of spinel ferrite, such as its high surface area, tunable bandgap, and excellent stability, contribute to its gas-sensing capabilities. The article then delves into recent advancements in gas sensors based on spinel ferrite, focusing on various aspects such as microstructures, element doping, and heterostructure materials. The microstructure of spinel ferrite can be tailored to enhance the gas-sensing performance by controlling factors such as the grain size, porosity, and surface area. Element doping, such as incorporating transition metal ions, can further enhance the gas-sensing properties by modifying the electronic structure and surface chemistry of the sensor material. Additionally, the integration of spinel ferrite with other semiconductors in heterostructure configurations has shown potential for improving the selectivity and overall sensing performance. Furthermore, the article suggests that the combination of spinel ferrite and semiconductors can enhance the selectivity, stability, and sensing performance of gas sensors at room or low temperatures. This is particularly important for practical applications where real-time and accurate gas detection is crucial. In conclusion, this review highlights the potential of spinel-ferrite-based gas sensors and provides insights into the latest advancements in this field. The combination of spinel ferrite with other materials and the optimization of sensor parameters offer opportunities for the development of highly efficient and reliable gas-sensing devices for early detection and warning systems.

Directly electrospun copper ferrite CuFe2O4 nanofiber-based for gas classification

“…In the (M 2+ )Fe 2 O 4 structure, the M 2+ cations are occupied at octahedral sites, while the Fe 3+ cations are evenly distributed between tetrahedral and octahedral sites [10,11]. The formation of defects in the crystal lattice structure, such as oxygen vacancies within the CuFe 2 O 4 (CFO) lattice in the synthesising procedure, in turn, promotes the absorption of gas molecules onto the surface of the material [12]. CFO has been employed as a promising candidate for sensing membranes in the literature due to its easy fabrication, low toxicity, and high thermal stability [13,14].…”