Natural
plant fibers such as cotton have favorable performance
in water and moisture management; however, they suffer from inferior
processing ability due to limited diameter and length, as well as
natural defects. Although commercially available regenerated cellulose
fibers such as lyocell fibers can have tunable structures, they rely
on the complete dissolution of cellulose molecules, including the
highly crystalline parts, leading to inferior mechanical properties.
Through a specially designed coaxial wet-spinning process, we prepare
a type of hollow fiber using only cellulose nanofibrils (CNFs) as
building blocks. It mimics cotton fibers with a lumen structure but
with a tunable diameter and a long length. Moreover, such hollow fibers
have superior mechanical properties with a Young’s modulus
of 24.7 GPa and tensile strength of 341 MPa, surpassing lyocell fibers
and most wet-spun CNF-based fibers. Importantly, they have 10 times
higher wicking ability, wetting rate, drying rate, and maximum wetting
ratio compared to lyocell fibers. Together with a superior long-term
performance after 500 rounds of wetting–drying tests, such
CNF-based hollow fibers are sustainable choices for advanced textile
applications. And this study provides a greater understanding of nanoscale
building blocks and their assembled macromaterials, which may help
to reveal the magic hierarchical design of natural materials, in this
case, plant fibers.