Recent Progress in Membrane Technologies Based on Metal–Phenolic Networks: A Review

Abstract

Metal–phenolic networks (MPNs) are novel supramolecular materials with numerous applications in the field of advanced material science and engineering due to their plentiful fascinating features. Following the first assembling of MPN films on diverse solid surfaces in 2013, MPN materials have attracted much attention in the membrane technology field to improve membrane multifunctionality through membrane surface or matrix modification for membrane structural stability, durability, and filtration efficiency enhancements. Moreover, the incorporation of inorganic nanomaterials, such as nanoparticles, nanotubes, nanorods, and nanosheets, and hydrophilic polymers, for instance, zwitterions and polyvinylpyrrolidone (PVP), can enable further improvements of MPN-based membranes for diverse water filtration applications. This review has critically summarized the recent MPN-based membrane modifications and identified areas that need to be considered in further research to enhance membrane durability, filtration performance, and operational lifetime. Overall, it is foreseen that the novel membranes, as well as an ever-widening scope of membrane applications based on the MPN material, will constantly emerge.

Biomimetic Sol–Gel Chemistry to Tailor Structure, Properties, and Functionality of Bionanocomposites by Biopolymers and Cells

“…Tannic acid, the entrapment of which provides intensely colored silica ( Figure 15 b,c), can also find application as a pH sensor since its spectral characteristics change significantly when the acidity of the medium is varied. Complexes with metal ions are especially suitable for this purpose [ 376 , 377 , 378 ]. Tannic acid has broad potential for various functionalization of bionanocomposites, in the pores of which it is left after biomimetic synthesis.…”