Recent Progress in C-C Bond Construction Based on 2(5<i>H</i>)-Furanone

王柏文,; 刘园,; 郝志峰,; 侯佳琦,; 李健怡,; 李舒婷,; 潘思慧,; 曾铭豪,; 汪朝阳,

doi:10.6023/cjoc201803053

Cited by 14 publications

(11 citation statements)

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“…Strengthening semiconductor/cocatalyst interfacial interaction is another appealing research direction to boost the elec- tron transfer from the semiconductor to the cocatalyst and subsequently accelerate the surface electrocatalytic H2 evolution over the cocatalysts. Generally, stronger interfacial interactions between semiconductors and cocatalysts could lead to a favorable interfacial effect on the electron-transfer process during photocatalysis, and are dependent on several important parameters that include the size, morphology, crystallinity, and composition of both the cocatalysts and the semiconductors, and their interfacial bonding and contact area [383,[500][501][502]. A simple method is to fabricate tight heterojunction interfaces through in situ high-temperature reactions.…”

Section: Strategies Based On Strengthening Interfacial Interactionmentioning

confidence: 99%

Ni-based photocatalytic H2-production cocatalysts2

Shen

Xie

Xiang

et al. 2019

Chinese Journal of Catalysis

255

108

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Photocatalysis is believed to be one of the best methods to realize sustainable H2 production. However, achieving this through heterogeneous photocatalysis still remains a great challenge owing to the absence of active sites, sluggish surface reaction kinetics, insufficient charge separation, and a high thermodynamic barrier. Therefore, cocatalysts are necessary and of great significance in boosting photocatalytic H2 generation. This review will focus on the promising and appealing low-cost Ni-based H2-generation cocatalysts as the alternatives for the high-cost and low-abundance noble metal cocatalysts. Special emphasis has been placed on the design principle, modification strategies for further enhancing the activity and stability of Ni-based cocatalysts, and identification of the exact active sites and surface reaction mechanisms. Particularly, four types of modification strategies based on increased light harvesting, enhanced charge separation, strengthened interface interaction, and improved electrocatalytic activity have been thoroughly discussed and compared in detail. This review may open a new avenue for designing highly active and durable Ni-based cocatalysts for photocatalytic H2 generation.

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Section: Strategies Based On Strengthening Interfacial Interactionmentioning

confidence: 99%

Ni-based photocatalytic H2-production cocatalysts2

Shen

Xie

Xiang

et al. 2019

Chinese Journal of Catalysis

255

108

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show abstract

“…More importantly, the nanosheet structure of ZIS6 facilitates the formation of a heterojunction between it and other catalysts that can promote the separation of photo-generated carriers, thereby increasing its photocatalytic activity [27]. It is currently accepted that noble metals (such as Pt [28,29], Au [30,31], Rh [32], and Pd [33,34]) can generally be applied as cocatalysts to enhance the separation efficiency of photoelectron-hole pairs. However, the limitation of noble metals is their high cost.…”

Section: Introductionmentioning

confidence: 99%

MoS2/Zn3In2S6 composite photocatalysts for enhancement of visible light-driven hydrogen production from formic acid

Zhang

Duan

Chen

et al. 2021

Chinese Journal of Catalysis

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“…However, the removal rate of TOC reaches up to 69.24% within 120 min using PNIPAM@Ag/Ag3PO4-20/CN. This indicates that the PNIPAM@Ag/Ag3PO4-20/CN photocatalyst has a higher mineralization efficiency for TC photodegradation than CN and Ag/Ag3PO4-20/CN [32].…”

Section: Tablementioning

confidence: 94%