Recent progress in application of nanocatalysts for carbonylative Suzuki cross-coupling reactions

Abstract

Cross-coupling of aryl halides and arylboronic acids in the presence of carbon monoxide, also called carbonylative Suzuki coupling, to form two new carbon–carbon bonds in the production of synthetically and biologically important biaryl ketones, has been widely studied.

Silver Natural Asphalt Sulfonate (NA-SO3Ag): Fabrication and Utilization as a New Heterogeneous, Carbonaceous, and Retrievable Nanocatalyst for C(sp2)-X (X = C, S, and Se) Bond Formation

“…Suzuki cross-coupling has attracted the greatest attention because of readily accessible, nontoxic, and stable aryl boronic acids and aryl halides. 17 indium, rhodium, and nickel, have been reported in this reaction. Cross-coupling aromatic halides and thiols in the presence of transition metals is the most common method for the synthesis of diaryl sulfides.…”

“…Transition-metal-catalyzed formation of C–C, C–S, and C–Se bonds by cross-coupling reactions is a powerful tool for the preparation of numerous important products in pharmaceutical, biological, and agrochemicals products. Suzuki cross-coupling has attracted the greatest attention because of readily accessible, nontoxic, and stable aryl boronic acids and aryl halides . Diaryl sulfides are a common component of natural products and are frequently utilized as crucial building blocks in organic transformations since they are biologically active compounds. − So far, various methods have been reported for the synthesis of diaryl sulfides.…”

“…Suzuki cross-coupling has attracted the greatest attention because of readily accessible, nontoxic, and stable aryl boronic acids and aryl halides. 17 Diaryl sulfides are a common component of natural products and are frequently utilized as crucial building blocks in organic transformations since they are biologically active compounds. 18 − 20 So far, various methods have been reported for the synthesis of diaryl sulfides.…”

Aryl fluorosulfates: powerful and versatile partners in cross-coupling reactions

“…8 Since a number of remarkable advances and developments in this domain have occurred during the past few decades, seems it is an appropriate time to summarize those discoveries in a comprehensive review. In continuation of our preceding works on cross-coupling reactions 10 and modern organic synthesis, 11 in this review, we intend to highlight the most important explorations and developments in the cross-coupling reactions using fluorosulfates from 1991 till today. For clarity, the topic is divided into two major parts.…”

Probing the nanoscale driving forces for adsorbate-induced Rh50Pd50 nanoparticle reconstruction via mean-field models of multi-faceted nanoparticles

“…Bimetallic nanoparticles are promising catalysts in the chemical industry for a wide range of catalytic processes, such as coupling, 1–3 oxidation, 4–6 and hydrogenation 7–10 reactions. Thanks to synergistic effects 11,12 that provide distinct geometric and electronic properties as compared to those of their monometallic parents, such bimetallic systems often exhibit enhanced catalytic performance.…”