Recent Progress and Prospects on Sodium-Ion Battery and All-Solid-State Sodium Battery: A Promising Choice of Future Batteries for Energy Storage
Kuangyi Shi,
Bin Guan,
Zhongqi Zhuang
et al.
Abstract:At
present, in response to the call of the green and renewable
energy industry, electrical energy storage systems have been vigorously
developed and supported. Electrochemical energy storage systems are
mostly comprised of energy storage batteries, which have outstanding
advantages such as high energy density and high energy conversion
efficiency. Among them, secondary batteries like lithium batteries,
sodium batteries, and lead-acid batteries have received wide attention
in recent years. Lithium-ion batteries… Show more
“…The preceding discussion has underscored the multiple factors influencing phase transitions, thus it is highly reasonable to tailor strategies for suppressing phase transitions based on these influences. Element doping is an effective strategy, which is often considered the most efficient method for suppressing phase transitions as it fundamentally alters the intrinsic properties of the material. For instance, it can modulate the material’s electronic structure, charge/ion state, energy band structure, and crystal structure to enhance structural stability and suppress phase transitions .…”
Section: Strategies For Inhibiting Phase Transitionmentioning
Sodium-ion batteries (SIBs) have great potential for large-scale energy storage devices due to the high abundance, wide distribution, and nontoxicity of the resource. Among the various cathode materials, layered oxides are considered a strong contender in the future SIBs market due to their open two-dimensional sodium ion diffusion channels, high theoretical capacity, and ease of synthesis. Unfortunately, layered oxides face phase transition during cycling, accompanied by severe electrochemical performance degradation, which greatly limits the long cycling stability. Therefore, it is of great significance to fully understand the mechanism, the origin, the influenced factors, and the inhibition strategies of phase transitions to develop a good cathode material. This review focuses on the phase transition in layered oxide cathodes, pointing out the intrinsic causes and degradation mechanisms of phase transition. Moreover, we summarize the mainstream strategies to inhibit the phase transition, such as elemental doping, surface coating, and structural modification, as well as the novel strategy of introducing anionic redox. We hope that this review provides new comprehension in understanding the phase transition of layered oxides and in designing SIBs with superior performance.
“…The preceding discussion has underscored the multiple factors influencing phase transitions, thus it is highly reasonable to tailor strategies for suppressing phase transitions based on these influences. Element doping is an effective strategy, which is often considered the most efficient method for suppressing phase transitions as it fundamentally alters the intrinsic properties of the material. For instance, it can modulate the material’s electronic structure, charge/ion state, energy band structure, and crystal structure to enhance structural stability and suppress phase transitions .…”
Section: Strategies For Inhibiting Phase Transitionmentioning
Sodium-ion batteries (SIBs) have great potential for large-scale energy storage devices due to the high abundance, wide distribution, and nontoxicity of the resource. Among the various cathode materials, layered oxides are considered a strong contender in the future SIBs market due to their open two-dimensional sodium ion diffusion channels, high theoretical capacity, and ease of synthesis. Unfortunately, layered oxides face phase transition during cycling, accompanied by severe electrochemical performance degradation, which greatly limits the long cycling stability. Therefore, it is of great significance to fully understand the mechanism, the origin, the influenced factors, and the inhibition strategies of phase transitions to develop a good cathode material. This review focuses on the phase transition in layered oxide cathodes, pointing out the intrinsic causes and degradation mechanisms of phase transition. Moreover, we summarize the mainstream strategies to inhibit the phase transition, such as elemental doping, surface coating, and structural modification, as well as the novel strategy of introducing anionic redox. We hope that this review provides new comprehension in understanding the phase transition of layered oxides and in designing SIBs with superior performance.
“…MXene, as a novel two-dimensional material, has widely used in the field of energy storage. Many researchers have described it. − But the most review papers only describe one metal battery or the preparation methods about MXene are very rough, which means that it is difficult for reader to master the other metal batteries and the preparation methods about MXene. − Moreover, some review articles have been published by scholars, covering many fields such as electrocatalysis, sodium ion batteries and all solid-state sodium batteries, supercapacitors. − However, there is little work about MXene, such as MXene-based supercapacitor, which means it is difficult for readers to grasp the application of MXene in metal batteries and the preparation methods of MXene. On the contrary, this review paper provides a detailed introduction to six preparation methods of MXene, such as HF etching, HCl and LiF etching, molten salt etching, electrochemical etching, deep eutectic solvent assisted etching, and alkaline etching, and presents the characteristics of these preparation methods and precursor MAX.…”
Lithium metal anodes are considered as one of the most promising choices for high-energy-density batteries owing to their high theoretical capacity (3860 mAh g −1 ) and low reduced anode potential [−3.04 V versus standard hydrogen electrode (SHE)]. However, the underlying safety risks of lithium metal batteries during cycling hinder their further development. MXenes have become a hot topic as a result of their excellent conductivity, flexibility, ultrafast ion diffusion, and large specific surface. Thus, MXene is vastly introduced in lithium metal batteries and lithium sulfur batteries for improving the safety and electrochemical performance of the entire battery. This review sights into the structural characteristics and different etching techniques about MXene and provides a detailed introduction to the shortcomings and challenges of lithium metal batteries and lithium−sulfur batteries. In addition, this review summarizes the applications of MXene and its composite materials in the modification strategies of lithium metal batteries and lithium−sulfur batteries and provides insights into the electrochemical application of MXene in other aqueous/non-aqueous energy storage systems.
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