Recent developments of the Stille reaction as a revolutionized method in total synthesis

Heravi, Majid M.; Hashemi, Elaheh; Azimian, Fereshteh

doi:10.1016/j.tet.2013.07.108

Cited by 125 publications

(55 citation statements)

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“…We also are kin to update the applications of name reactions in the total synthesis of natural products [118][119][120][121][122][123][124][125][126][127][128] and applications of different synthons, reagents and catalysts in organic synthesis [129][130][131][132][133][134][135] .…”

Section: Introductionmentioning

confidence: 99%

Isocyanide-based multicomponent reactions in the synthesis of heterocycles

2016

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Section: Introductionmentioning

confidence: 99%

Isocyanide-based multicomponent reactions in the synthesis of heterocycles

2016

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“…32 We are interested in the asymmetric synthesis, [35][36][37][38][39][40][41][42][43] and applications of named reactions in the total synthesis of natural products which usually use asymmetric synthesis in one or more steps in their multi-step synthesis. [44][45][46][47][48] Due to the increasing number of articles published concerning asymmetric 1,4-addition reactions, catalyzed by Rh-complexes, we were prompted to update the invaluable review by Hayashi et al in 2003. 32 Herein we highlight the recent advances in Rhcomplex asymmetric catalyzed 1,4-addition reactions from 2003 to date.…”

Section: Introductionmentioning

confidence: 99%

Rh-catalyzed asymmetric 1,4-addition reactions to α,β-unsaturated carbonyl and related compounds: an update

Heravi

Dehghani

Zadsirjan

2016

Tetrahedron: Asymmetry

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Rh-catalyzed asymmetric 1,4-addition reactions to a,b-unsaturated carbonyl and related compounds: an update Available online xxxx Dedicated to my son, OMID on the occasion of his 35th birthday. a b s t r a c tThe Rh-catalyzed asymmetric 1,4-addition of organometallic reagents to an appropriate receptor has been a growing area of research over the last decade. The receptors for such a 1,4-addition reaction are chiefly a,b-unsaturated ketones, esters, amides, enones, nitroalkenes, and occasionally phosphonates etc. This reaction in the presence of chiral rhodium complexes introduce the aryl and alkenyl groups at the b-position of the above electron poor olefins, enantioselectively. Chiral Rh complexes similar to other transition metals can be added to some electron poor olefins, in turn making them viable to attack by various organometallic reagents for highly enantioselective C-C bond formation. The Rh-catalyzed asymmetric 1,4-addition of organometallic reagents to electron poor olefins has been reviewed in 2003. Due to the importance of the asymmetric C-C bond formation via 1,4-conjugate addition reactions and the number of such reactions catalyzed by Rh-complexes, in this review we highlight the recent advances in Rh-complex asymmetric catalyzed 1,4-addition reactions since 2003.

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“…A literature survey revealed several useful reviews on the synthesis of imidazoles [22][23][24][25][26]-among them a comprehensive review published in Tetrahedron in 2007 [22]. We are involved in heterocyclic chemistry [27][28][29][30][31][32][33][34] and focus on enhancing recent developments and progress in organic chemistry especially in the area of name reactions [35][36][37][38]. In line with our interest, considering the importance of the imidazole moiety and prompted by the mentioned comprehensive review [22], we aimed for an update and extension of its usefulness focusing on the synthesis of imidazoles.…”

Section: Introductionmentioning

confidence: 99%