In this study, titanium diboride (TiB2) with silicon carbaid (SiC) nano particles as a sintering aid was isostatic-pressed, then sintered at a temperature of 1800°C. The amount of SiC had a significant influence on the sinterability and mechanical properties of TiB2. When a small amount (10 wt%) of SiC was added, SiC reacted with titania (TiO2) that was present on the surface of TiB2 powder to form titanium carbaid (TiC) and amorphous silica (SiO2). Elimination of TiO2 suppressed the grain growth effectively, which led to an improvement in the densification of TiB2. Vickers hardness was enhanced remarkably through these improvements in the sinterability and microstructure. On the other hand, when a large amount (≥10 wt%) of SiC was added, the density and hardness were not improved much, presumably because of the extensive formation of SiC phase at the grain boundaries.