“…[18][19][20] Recently,t he US Department of Energy( DOE), DuPont Industrial Bioscience, and Archer Daniels Midland Co. have declared FDCA as one of the most important valueadded chemicals, which has the potential to generate exciting high-performance renewable materials in the 21 st century. [25,26] Despite the potentiala pplication of FDCA-based polymers such as polyesters, [27] polyamides, [28] and epoxy resins [29] in the production of bioplastics, [30] 3D printing, [31] coatings in automotive and marine industries, [32] and in the fabrication of biomedical devices, [33] the environmentally friendly synthesis of bio-based polymers and advanced methods for the generationo fh ighmolecular-weight polymers have not been exploredc ompletely.M ost of the protocols reported for the synthesis of biobased polymers that display variousp hysical and chemical properties involveh arsh reaction conditions, metal catalysts, and intense purification steps. [25,26] Despite the potentiala pplication of FDCA-based polymers such as polyesters, [27] polyamides, [28] and epoxy resins [29] in the production of bioplastics, [30] 3D printing, [31] coatings in automotive and marine industries, [32] and in the fabrication of biomedical devices, [33] the environmentally friendly synthesis of bio-based polymers and advanced methods for the generationo fh ighmolecular-weight polymers have not been exploredc ompletely.M ost of the protocols reported for the synthesis of biobased polymers that display variousp hysical and chemical properties involveh arsh reaction conditions, metal catalysts, and intense purification steps.…”