Recent Applications of Oxazoline-Containing Ligands in Asymmetric Catalysis

Application of Hydroxyporphyrins-based Phosphite-type Ligands to Asymmetric Pd-Catalyzed Allylic Substitution Reactions

“…[1][2][3][4][5][6] Activity and enantioselectivity of the metal complex catalysts are determined to a great extent by a proper design and synthesis strategy of the corresponding chiral ligands, first of all, phosphorus containing ligands, thousands representatives of which were used in various asymmetric transformations. [1][2][3][4][5][6][7][8][9][10][11][12][13] However, elaboration of an efficient asymmetric inductor for a given catalytic process often represents a challenge. The vast majority of known phosphorus-based chiral ligands in the corresponding metal complexes are able to catalyze (with different enantioselectivities) either a certain type of chemical transformation, or one certain reaction.…”

Synthesis and application of new iminopyridine ligands in the enantioselective palladium-catalyzed allylic alkylation

“…Most of them are mixed bidentate donor ligands with P-P or P-N chelating mode [1][2][3][4][5][6], although several interesting examples of N,N-chelating ligands such as diamines [7], pyridine-based ligands (2,2 -bipyridines, 1,10-phenanthrolines, pyridyl amines, pyridyl oxazolines, etc.) [8] and oxazoline-containing ligands [9] have also proven their efficiency.…”

Synthesis of MeO-PEG-Supported Ferrocenyloxazoline Ligands and Their Application in Asymmetric Catalysis

“…[15][16][17] Among them, planar chiral ferrocenyloxazoline derived chiral N,P ligands and N,S ligands are versatile, and have a wide range of applications in asymmetric catalysis. Very recently, our group mainly focused on chiral bifunctional AgOAc catalyzed asymmetric reactions under the mild neutral condition, [18][19][20] for examples, asymmetric 1,3-dipolar cycloaddition reaction of azomethine ylides, asymmetric Mannich-type reactions and asymmetric aminations.…”