“…In this domain, considering the importance of synthesizing functionalized olefins, 1,2‐difunctionalization reaction of naturally abundant alkynes has been established as an important subset which enables the construction of stereodefined tri‐ and tetra‐substituted alkenes by syn ‐ or anti ‐selective introduction of two functional groups across the triple bond [1b,d,f,g,p,q] . Given the ubiquity of nitrogen‐containing molecules in nature serving as versatile building blocks for many pharmaceuticals, natural products, commodity chemicals and functional materials, 1,2‐aminofunctionalization reactions of alkynes have evolved as a thriving area of research [1f,g,l,q,2a,3a,b,4a] . Noteworthily, these aminofunctionalization reactions have been applied in achieving various annulation reactions for the synthesis of wide range of heterocyclic scaffolds highlighting the potential of these carbophilic activation strategies.…”