Recent Advances in the Synthesis, Characterization, and Applications of Fulleropyrrolidines

Kharisov, Boris I.; Kharissova, Oxana V.; Gomez, Marco Jimenez; Méndez, Ubaldo Ortiz

doi:10.1021/ie800602j

Cited by 48 publications

(27 citation statements)

References 161 publications

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“…The use of other N-substituted glycines instead of sarcosine makes it possible to introduce two different substituents into the pyrrolidine ring. The Prato reaction has a diverse range of applications in the field of organic materials; many comprehensive reviews [2][3][4][5][6][7] and books [8][9][10][11] are available on the topic.…”

Section: Synthesis Of Covalently Linked Conjugates Of C 60 Fullerenementioning

confidence: 99%

Synthesis, Properties, and Potential Applications of Porphyrin-Fullerenes

Mironov¹

2011

MHC

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The review focuses current research in the rapidly developing chemistry of porphyrin-fullerene complexes, and highlights recent advances in the synthesis, properties, and potential applications of this family. An overview of the most popular methods to prepare porphyrin complexes with C 60 fullerene exhibiting various types of linkage is given with the main focus on the Prato reaction and its modifications. The discussion of porphyrin-fullerene complexes will include the structures of noncovalently linked porphyrin-fullerenes along with the covalently linked complexes; the chemistry and design of supramolecular ensembles will be covered rather comprehensively. Finally, the potential applications for porphyrin-fullerene conjugates will be discussed.

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Section: Synthesis Of Covalently Linked Conjugates Of C 60 Fullerenementioning

confidence: 99%

Synthesis, Properties, and Potential Applications of Porphyrin-Fullerenes

Mironov¹

2011

MHC

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“…[1][2][3][4][5] One of the unique aspects of fullerenes in this field is the formation of interfullerene bondings, which makes a rich variety of nanoscale network structures such as dimers, oligomers, and one-and two-dimensional fullerene polymeric materials.…”

Section: Introductionmentioning

confidence: 99%

Fullerene Dimers Connected through C₂₄and C₃₆Bridge Cages

Anafcheh¹,

Ghafouri²

2014

Bulletin of the Korean Chemical Society

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We have performed DFT calculations to devise some possible fullerene dimers (from C60 and C80) connected through C24 and C36 bridge cages with the face-to-face linking model. The fullerene dimers with C36 bridges have lower binding energies and greater HOMO-LUMO gaps than those of the fullerene dimers with C24 bridges. Also, the replacement of C60 cages with C80 ones always leads to an increase in binding energies and HOMO-LUMO gaps in these systems. Dimerization of C60 and C80 fullerenes with C24 and C36 results in a significant decrease in antiaromaticity of the antiaromatic cages C24 and C80, and an increase in the aromaticity of the aromatic cages C36 and C60. Therefore, DFT results indicate that those fullerene dimers involving the initially harshly antiaromatic C24 or C80 cages are more energetically favorable configuration than the fullerene dimers involving the aromatic C36 and C60 cages.

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“…Однако он образует различные по природе диады с молекулами -донорами электронов, таким как тетратиафульвалены, металлоцены, N,N-диметиламинофенил-производные, рутений(II)-трис-бипиридин, порфирины, фталоцианины, являющиеся предметом многочисленных исследований. [2][3][4][5][6][7][8][9][10][11] Значительный интерес представляют порфирин-фуллереновые диады, образованные за счет донорно-акцепторного координационного взаимодействия между электронодонорным атомом заместителя в фуллерене и атомом металла в металлопорфирине. Пиридильные или имидазольные производные пирролидинил- [60] фуллерена имеют дополнительные реакционные центры и могут выступать донорами электронной плотности по отношению к координационно ненасыщенным металлопорфиринам (MP), образуя с ними координационно-связанные диады [12][13][14][15] и молекулярные комплексы более высокого порядка.…”

Section: Introductionunclassified