Recent advances in the synthesis of zirconium complexes and their catalytic applications

Asim, Wasifa; Waheeb, Azal Shakir; Awad, Masar Ali; Kadhum, Afaf Murtada; Ali, Asjad; Mallah, Shaimaa Hassan; Iqbal, Muhammad Adnan; Kadhim, Mustafa M.

doi:10.1016/j.molstruc.2021.131925

Cited by 4 publications

(2 citation statements)

References 179 publications

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“…Zirconium oxide-based diaphragms offer several advantages over other types of diaphragms, including high chemical and thermal stability, excellent corrosion resistance, and a long service life. These properties make them an ideal choice for use in alkaline electrolyzers, where they can help to improve the efficiency and durability of the device [14]- [16].…”

Section: Introductionmentioning

confidence: 99%

Investigative study of cost-effective ZrO₂ nanoparticles/acrylic based diaphragm for alkaline electrolyzers

Zainul,

Qayoom,

Ahmad

et al. 2023

IOP Conf. Ser.: Earth Environ. Sci.

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Energy is crucial to the cycle of existence in the universe and plays an important role in achieving sustainable growth. Considering the traits of the conventional approach and challenges dealing with conventional energy technologies, water electrolysis is reflected to be simple, sustainable, and green energy tool. Alkaline water electrolysis (AWE) process is mature technology of the last century for industrial hydrogen production. AWE uses asbestos as the separator medium. However, asbestos allows crossover of the produced gases therefore, low purity gas is obtained, and with limited stability. In the present study, a novel composite diaphragm separator has been synthesized using Zirconium oxide (ZrO2) with aqueous acrylic solution in different compositions and optimized for enhanced performance. The prepared composite is initially stabilized through sonication and applied on the medium with a uniform thickness using a doctor blade film applicator. The study aims to optimize the composite diaphragm to withstand the severe chemical and thermal conditions of the electrolyzer. Zirconium oxide-based diaphragms offer several advantages over other types of diaphragms, including excellent corrosion resistance, high chemical and thermal stability, and long service life. These coated separator diaphragms showed good electrolysis performance and stability in an alkaline medium.

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Section: Introductionmentioning

confidence: 99%

Investigative study of cost-effective ZrO₂ nanoparticles/acrylic based diaphragm for alkaline electrolyzers

Zainul,

Qayoom,

Ahmad

et al. 2023

IOP Conf. Ser.: Earth Environ. Sci.

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“…optically active compounds or polymers with well-dened tacticity. [37][38][39] Ansa-zirconocene amide complexes have been reported by Jordan et al, who demonstrated the selective synthesis of [rac/meso-(ebi)Zr(NMe 2 ) 2 ] (ebi ¼ 1,2-ethylene-1,1 0bis(h 5 -indenyl)) by amine elimination. 40,41 Likewise, this route furnishes other zirconocene amide complexes with an indenyl ligand system.…”

Section: Introductionmentioning

confidence: 99%

Mono- and dinuclear zirconocene(iv) amide complexes for the catalytic dehydropolymerisation of phenylsilane

et al. 2022

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Catalytic potential of sustainable dinuclear (Cu2+ and ZrO2+) metal organic incorporated frameworks with comprehensive biological studies

Adam

Sedky

Makhlouf

et al. 2023

Journal of the Taiwan Institute of Chemical Engineers

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Recent advances in the synthesis of zirconium complexes and their catalytic applications

Cited by 4 publications

References 179 publications

Investigative study of cost-effective ZrO₂ nanoparticles/acrylic based diaphragm for alkaline electrolyzers

Investigative study of cost-effective ZrO₂ nanoparticles/acrylic based diaphragm for alkaline electrolyzers

Mono- and dinuclear zirconocene(iv) amide complexes for the catalytic dehydropolymerisation of phenylsilane

Catalytic potential of sustainable dinuclear (Cu2+ and ZrO2+) metal organic incorporated frameworks with comprehensive biological studies

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Recent advances in the synthesis of zirconium complexes and their catalytic applications

Cited by 4 publications

References 179 publications

Investigative study of cost-effective ZrO2 nanoparticles/acrylic based diaphragm for alkaline electrolyzers

Investigative study of cost-effective ZrO2 nanoparticles/acrylic based diaphragm for alkaline electrolyzers

Mono- and dinuclear zirconocene(iv) amide complexes for the catalytic dehydropolymerisation of phenylsilane

Catalytic potential of sustainable dinuclear (Cu2+ and ZrO2+) metal organic incorporated frameworks with comprehensive biological studies

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Investigative study of cost-effective ZrO₂ nanoparticles/acrylic based diaphragm for alkaline electrolyzers

Investigative study of cost-effective ZrO₂ nanoparticles/acrylic based diaphragm for alkaline electrolyzers