Recent Advances in the Preparation of Air Stable Organozinc Pivalates and their Applications in Organic Synthesis
Vasudevan Dhayalan,
Vishal S. Dodke,
Deepika Sharma
et al.
Abstract:This review discusses various methods for the preparation of air and water‐stable organozinc pivalates containing aryl, heteroaryl, alkyl, alkenyl, benzyl and alkynyl scaffolds achieved via i) selective metalation (DoM) in the presence of a directing group (DG) in the aromatic core, ii) direct oxidative Zn metal insertion/or X/M exchange reaction followed by transmetalation with Zn(Opiv)2, which are then further functionalized by Negishi cross‐coupling reactions, or trapping with different aryl, heteroaryl,… Show more
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