Recent advances in the mechanisms of the hydrogen evolution reaction by non-innocent sulfur-coordinating metal complexes

Δρόσου, Μαρία; Kamatsos, Fotios; Mitsopoulou, Christiana A.

doi:10.1039/c9qi01113g

Cited by 67 publications

(67 citation statements)

References 179 publications

(193 reference statements)

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“…In order to realize scientific and reasonable decision-making, it is necessary to change the thinking of decision-makers into the practical decision-making thought with the highest interests of regions and departments and establish the decision-making idea of taking economic development as the priority and taking sustainable development as the goal in order to maximize the limited aquatic resources. It not only meets the needs of current economic development but also provides the possibility of foreseeable sustainable development in the future, so as to generate the maximum benefits [19,20]. Sustainable development is the basic basis and principle of adjusting the interests of various departments and the ultimate goal of making scientific decisions.…”

Section: Operation Rules Of Comprehensive Management and Coordinationmentioning

confidence: 99%

Comprehensive Management and Coordination Mechanism of Marine Economy

Jing-zhen

Xia

Wang

2021

Mathematical Problems in Engineering

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With the rapid development of economy and society and the continuous progress of science and technology, the public demand for marine products and services is increasing, and the marine economic and social benefits are rising. It is very important to improve the management level of marine economy. The purpose of this study is to analyze the comprehensive management and coordination mechanism of China’s marine economy. This study selects Lianyungang City as the research object and takes the marine economic data from 2010 to 2019 as the research data. This study establishes three evaluation index systems of marine economic development. Then, according to the influence of the marine industry development, social development, population, marine resources and environment, regional scientific and technological innovation ability, government comprehensive management, and other factors on the regional marine economic management, this paper puts forward a set of marine economy comprehensive coordination management system and method and evaluates the current situation of marine economic development in Lianyungang City. The results show that, in the 10 years from 2010 to 2019, the comprehensive management evaluation value of China’s marine economy has increased from 0.20 to 0.33, with an average annual increase of 6.57 percentage points. The system level has been upgraded from the initial “poor” to “average,” achieving rapid growth. It is concluded that the index system evaluation of this study well reflects the change of the management level of China’s marine economy and has a promoting effect on the development of China’s marine economy, making contributions to China’s economic management.

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Section: Operation Rules Of Comprehensive Management and Coordinationmentioning

confidence: 99%

Comprehensive Management and Coordination Mechanism of Marine Economy

Jing-zhen

Xia

Wang

2021

Mathematical Problems in Engineering

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“…48 In the past few decades, coordination chemistry has widely contributed to the research field of electrocatalysts for water reduction based on the synthesis of new coordination compounds. 49 Early works on the hydrogen evolution system started from Prussian white which was homometallic Fe II CP. 50,51 Note that it is easy to incorporate two kinds of metal ions into Prussian blue analogues by mixing hexacyanido complexes and metal ions in a self-assembly method because many types of hexacyanido complexes with different metal centres have been discovered.…”

Section: H 2 Evolution Electrocatalysismentioning

confidence: 99%

Heterometallic coordination polymers as heterogeneous electrocatalysts

Kuwamura

Konno

2021

Inorg. Chem. Front.

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“…Homogeneous square planar, redox active MX 4 (X = S, N, O) complexes have been actively studied for various electrocatalytic applications. 89 , 90 Among them, Co-dithiolene molecular systems have been widely reported for the photochemical and electrochemical HER. 91 − 93 Inspired by those molecular catalytic systems, Clough et al incorporated the Co-dithiolene species to extended 2D metal organic surfaces (MOSs) [Co 3 (BHT) 2 ] 3– (MOS1, BHT = benzenehexatiol) and [Co 3 (THT) 2 ] 3– (MOS2, THT = triphenylene-2,3,6,7,11,12-hexanethiol) ( Figure 4 a).…”

Section: Extending Molecular Active Sites Into Framework Materialsmentioning

confidence: 99%

From Molecules to Porous Materials: Integrating Discrete Electrocatalytic Active Sites into Extended Frameworks

et al. 2020

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Metal–organic and covalent–organic frameworks can serve as a bridge between the realms of homo- and heterogeneous catalytic systems. While there are numerous molecular complexes developed for electrocatalysis, homogeneous catalysts are hindered by slow catalyst diffusion, catalyst deactivation, and poor product yield. Heterogeneous catalysts can compensate for these shortcomings, yet they lack the synthetic and chemical tunability to promote rational design. To narrow this knowledge gap, there is a burgeoning field of framework-related research that incorporates molecular catalysts within porous architectures, resulting in an exceptional catalytic performance as compared to their molecular analogues. Framework materials provide structural stability to these catalysts, alter their electronic environments, and are easily tunable for increased catalytic activity. This Outlook compares molecular catalysts and corresponding framework materials to evaluate the effects of such integration on electrocatalytic performance. We describe several different classes of molecular motifs that have been included in framework materials and explore how framework design strategies improve on the catalytic behavior of their homogeneous counterparts. Finally, we will provide an outlook on new directions to drive fundamental research at the intersection of reticular-and electrochemistry.

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Recent advances in the mechanisms of the hydrogen evolution reaction by non-innocent sulfur-coordinating metal complexes

Abstract: This review comments on the homogeneous HER mechanisms for catalysts carrying S-non-innocent ligands in the light of experimental and computational data.

Cited by 67 publications

References 179 publications

Comprehensive Management and Coordination Mechanism of Marine Economy

Comprehensive Management and Coordination Mechanism of Marine Economy

Heterometallic coordination polymers as heterogeneous electrocatalysts

From Molecules to Porous Materials: Integrating Discrete Electrocatalytic Active Sites into Extended Frameworks

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