Recent advances in synthesis of polymers based on palm oil and its fatty acids

Stavila, Erythrina; Yuliati, Frita; Adharis, Azis; Laksmono, Joddy Arya; Iqbal, Muhammad

doi:10.1039/d3ra01913f

Cited by 11 publications

(2 citation statements)

References 165 publications

(259 reference statements)

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“…Natural seed oils are particularly attractive as renewable materials. These low-cost naturally occurring feedstocks owing to their functional groups make them a useful component that can be employed for the synthesis of value-added products . In the context of industrial-scale production, the transformation of vegetable oils has significant potential to lead to a sustainable process of replacing some of the chemicals derived from crude oil.…”

Section: Introductionmentioning

confidence: 99%

Inhibition of the Decomposition Pathways of Ruthenium Olefin Metathesis Catalysts: Development of Highly Efficient Catalysts for Ethenolysis

Gawin,

Tracz,

Krajczy

et al. 2023

J. Am. Chem. Soc.

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Ruthenium-based Hoveyda-type olefin metathesis catalysts bearing novel rigid spirocyclic alkyl amino carbenes (CAACs) have been developed. They are characterized by exceptional stability toward decomposition through β-elimination and bimolecular pathways, thus enabling unprecedented efficiency in the cross-metathesis of seed oil-derived fatty acid esters with ethylene (ethenolysis). Catalyst loading as low as 100 ppb was applied to the ethenolysis of the model substrate methyl oleate, leading to a remarkable turnover number (TON) of 2.6 million, significantly higher than previously reported (TON 340 000 at 1 ppm and 744 000 at 0.5 ppm catalyst loading). Ethenolysis of methyl esters derived from high oleic sunflower oil and rapeseed oil, readily available on an industrial scale, inexpensive, and renewable feedstocks, was for the first time effectively carried out with 0.5 ppm catalyst loading with TON as high as 964 000.

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Section: Introductionmentioning

confidence: 99%

Inhibition of the Decomposition Pathways of Ruthenium Olefin Metathesis Catalysts: Development of Highly Efficient Catalysts for Ethenolysis

Gawin,

Tracz,

Krajczy

et al. 2023

J. Am. Chem. Soc.

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“…The relevance of research is due to the need to: -ensure the sustainable development of society and global problems of today, which require the creation of ecologically appropriate resource-saving (regarding fossil petrochemical raw materials) technologies for obtaining polymeric materials,weakening the dependence on hydrocarbon raw materials, which meets the requirements of "green chemistry" in the creation polymer materials that are widely used in various industries [1][2][3].…”

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confidence: 99%

Ecologically friendly water-based polyuretnanes materials

Savelyev,

Robota,

Brykova

2024

InterConf+

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Bioplastic: an eco‐friendly alternative to non‐biodegradable plastic

Mangal,

Rao,

Banerjee

2023

Polymer International

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The accumulation of non‐biodegradable plastic waste in land and aquatic environments is expanding every day. According to data collected from various scientific reports, about 100–250 megatonnes of plastic waste arrives in the oceans annually. According to the Central Control Board of India (2019–2020), India produces about 3.5 million metric tonnes of plastic waste annually, while only 5–10% of the produced waste is recycled. The non‐recycled plastic waste dumped into the environment either goes to landfills or directly goes to the sea, which disrupts the marine life of the ocean. We are highly dependent on plastic at household and industrial scales. Removal of plastic waste and lowering the use of hazardous and non‐biodegradable plastics are the main challenges. Researchers and industrialists have come up with many ideas to lower the generation of non‐biodegradable plastic waste and found that reusability is easier than degradability, while the use of bioplastics is the ultimate solution to tackle the plastic waste problem. Hence, developing eco‐friendly alternative plastics without compromising physicochemical and mechanical properties is the need of the hour. An eco‐friendly alternative to conventional or petrochemical plastics is bioplastics, which are environmentally safe, and reduce our dependency on fossil reserves. Therefore, this review focuses on eco‐friendly bioplastics as an efficient alternative to non‐biodegradable plastics. Among renewable and sustainable feedstocks available, vegetable oils are the most suitable resource for bioplastic production because of their renewability and economical nature. Hence, this study concluded that polyurethane‐based polymers from vegetable oils are inherently more eco‐friendly than most other plastics. © 2023 Society of Industrial Chemistry.

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Recent advances in synthesis of polymers based on palm oil and its fatty acids

Abstract: Triglycerides and fatty acids in palm oil and their derivatives can be utilized as bio-based monomers for synthesizing polymers.

Cited by 11 publications

References 165 publications

Inhibition of the Decomposition Pathways of Ruthenium Olefin Metathesis Catalysts: Development of Highly Efficient Catalysts for Ethenolysis

Inhibition of the Decomposition Pathways of Ruthenium Olefin Metathesis Catalysts: Development of Highly Efficient Catalysts for Ethenolysis

Ecologically friendly water-based polyuretnanes materials

Bioplastic: an eco‐friendly alternative to non‐biodegradable plastic

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